2633-57-0

• 常用中文名：三烯丙基(苯基)硅烷
• 常用英文名：Phenyltriallylsilane
• CAS号：2633-57-0
• 分子式：C₁₅H₂₀Si
• 分子量：228.40500
• 发布时间：2016-11-10 20:30:58
• 更新时间：2024-01-13 19:44:53

名称

• 中文名: 三烯丙基(苯基)硅烷
• 英文名: phenyl-tris(prop-2-enyl)silane
• 英文别名: Triallyl-phenyl-silan; phenyltriallylsilane; triallyl-phenyl-silane

物化性质

• 密度: 0.88g/cm3
• 沸点: 142ºC
• 分子式: C₁₅H₂₀Si
• 分子量: 228.40500
• 闪点: 118.1ºC
• 精确质量: 228.13300
• LogP: 3.90040
• 外观性状: 无色液体
• 蒸汽压: 0.00276mmHg at 25°C
• 折射率: 1.501
• 储存条件:

  密封储存，储存于阴凉、干燥的库房。

• 计算化学:

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:0

  3.氢键受体数量:0

  4.可旋转化学键数量:7

  5.互变异构体数量:无

  6.拓扑分子极性表面积0

  7.重原子数量:16

  8.表面电荷:0

  9.复杂度:209

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:1

• 更多:

  1. 性状：无色液体

  2. 密度（g/mL,25℃）：未确定

  3. 相对蒸汽密度（g/mL,空气=1）：未确定

  4. 熔点（ºC）：未确定

  5. 沸点（ºC,常压）：142

  6. 沸点（ºC,29mmHg）：未确定

  7. 折射率(n20/D)：未确定

  8. 闪点（ºC）：未确定

  9. 比旋光度（º）：未确定

  10. 自燃点或引燃温度（ºC）：未确定

  11. 蒸气压（mPa,20ºC）：未确定

  12. 饱和蒸气压（kPa,25ºC）：未确定

  13. 燃烧热（KJ/mol）：未确定

  14. 临界温度（ºC）：未确定

  15. 临界压力（KPa）：未确定

  16. 油水（辛醇/水）分配系数的对数值：未确定

  17. 爆炸上限（%,V/V）：未确定

  18. 爆炸下限（%,V/V）：未确定

  19. 溶解性：未确定

MSDS

Name: Phenyltriallylsilane Material Safety Data Sheet Synonym: CAS: 2633-57-0 Section 1 - Chemical Product MSDS Name:Phenyltriallylsilane Material Safety Data Sheet Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS CAS# Chemical Name content EINECS# 2633-57-0 Phenyltriallylsilane unlisted Hazard Symbols: T Risk Phrases: 23/24/25 48 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Toxic by inhalation, in contact with skin and if swallowed. Danger of serious damage to health by prolonged exposure. Potential Health Effects Eye: May cause eye irritation. Skin: Toxic in contact with skin. Ingestion: Poison by ingestion. The toxicological properties of this substance have not been fully investigated. Inhalation: The toxicological properties of this substance have not been fully investigated. Toxic if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid immediately. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use foam, dry chemical, or carbon dioxide. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Section 7 - HANDLING and STORAGE Handling: Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 2633-57-0: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: Not available. Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 142 deg C @ 760.00m Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: Molecular Weight: 216.23 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Not available. Incompatibilities with Other Materials: Not available. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 2633-57-0 unlisted. LD50/LC50: Not available. Carcinogenicity: Phenyltriallylsilane - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: T Risk Phrases: R 23/24/25 Toxic by inhalation, in contact with skin and if swallowed. R 48 Danger of serious damage to health by prolonged exposure. Safety Phrases: S 28 After contact with skin, wash immediately with... S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S 38 In case of insufficient ventilation, wear suitable respiratory equipment. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 2633-57-0: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 2633-57-0 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 2633-57-0 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A

安全

• 危害码 (欧洲): T: Toxic;
• 风险声明 (欧洲): R48
• 安全声明 (欧洲): 45-38-36/37/39-28A
• 海关编码: 2931900090

合成路线

98-13-5 1730-25-2 ~93% 2633-57-0

文献：Andres, Roman; De Jesus, Ernesto; De La Mata, F. Javier; Flores, Juan C.; Gomez, Rafael European Journal of Inorganic Chemistry, 2005 , # 18 p. 3742 - 3749

2622-05-1 98-13-5 ~96% 2633-57-0

文献：Zhang, Daohong; Liang, Enbin; Li, Tingcheng; Chen, Sufang; Zhang, Junheng; Cheng, Xinjian; Zhou, Jiliang; Zhang, Aiqing RSC Advances, 2013 , vol. 3, # 24 p. 9522 - 9529

98-13-5 106-95-6 ~61% 2633-57-0

文献：Ramesh, Remya; Reddy, D. Srinivasa Organic and Biomolecular Chemistry, 2014 , vol. 12, # 24 p. 4093 - 4097

98-13-5 346713-20-0 ~96% 2633-57-0

文献：Li, Zhifang; Cao, Xiaojun; Lai, Guoqiao; Liu, Jinhua; Ni, Yong; Wu, Jirong; Qiu, Huayu Journal of Organometallic Chemistry, 2006 , vol. 691, # 22 p. 4740 - 4746

6157-41-1 1730-25-2 ~54% 2633-57-0

文献：Boudin, Alain; Cerveau, Genevieve; Chuit, Claude; Corriu, Robert J. P. Bulletin of the Chemical Society of Japan, 1988 , vol. 61, # 1 p. 101 - 106

98-13-5 107-05-1 ~% 2633-57-0

文献：Zhang, Daohong; Liang, Enbin; Li, Tingcheng; Chen, Sufang; Zhang, Junheng; Cheng, Xinjian; Zhou, Jiliang; Zhang, Aiqing RSC Advances, 2013 , vol. 3, # 9 p. 3095 - 3102

上下游产品

上游产品  7
98-13-5 1730-25-2 2622-05-1 106-95-6
346713-20-0 6157-41-1 107-05-1
下游产品  10
106291-23-0 3597-91-9 321-60-8 92-93-3
92-67-1 643-58-3 605-02-7 2404-87-7
2051-60-7 86-26-0

海关

海关编码	2931900090
中文概述	2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%
Summary	2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%