Controlled introduction of allylic group to chlorosilanes

Z Li, X Cao, G Lai, J Liu, Y Ni, J Wu, H Qiu

文献索引：Li, Zhifang; Cao, Xiaojun; Lai, Guoqiao; Liu, Jinhua; Ni, Yong; Wu, Jirong; Qiu, Huayu Journal of Organometallic Chemistry, 2006 , vol. 691, # 22 p. 4740 - 4746

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被引用次数: 1

摘要

Allylation of chlorosilanes has been achieved with allylsamarium bromide, especially in a controlled manner. Thus allylation of trisubstituted chlorosilanes (R3SiCl) afforded a variety of aryl, aralkyl, and alkenyl substituted allylsilanes. Dichlorosilanes (R2SiCl2) can either afford monoallylated silanes or diallylated silanes depending on the amount of allylsamarium bromide used. Similarly, trichlorosilanes (RSiCl3) can selectively afford ...