Journal of Organometallic Chemistry

Selective mono-and di-allylation and allenylation of chlorosilanes using indium

Z Li, C Yang, H Zheng, H Qiu, G Lai

文献索引：Li, Zhifang; Yang, Chenjun; Zheng, Hongfang; Qiu, Huayu; Lai, Guoqiao Journal of Organometallic Chemistry, 2008 , vol. 693, # 25 p. 3771 - 3779

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被引用次数: 0

摘要

Allyl and allenyl groups have been introduced into silicon systems by the allylation and allenylation of chlorosilanes using allyl bromide or propargyl bromide with indium. The allylation of chlorosilanes afforded a variety of aryl, aralkyl, and alkenyl substituted allylsilanes. By applying this method, the reactions of 1-bromo-3-methylbut-2-ene, 3-bromo- 2-methylprop-1-ene and 3-bromobut-1-ene with chlorosilanes also proceed smoothly to ...