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| 中文名 | 烯丙基溴化镁 |
|---|---|
| 英文名 | Allylmagnesium bromide |
| 中文别名 | 烯丙基溴化镁 |
| 英文别名 |
Allylmagnesium bromide
Magnesium, bromo-2-propen-1-yl- Allyl(bromo)magnesium MFCD00000044 |
| 密度 | 0.851 |
|---|---|
| 分子式 | C3H5BrMg |
| 分子量 | 145.281 |
| 闪点 | -40ºC |
| 精确质量 | 143.942490 |
| LogP | 1.98560 |
| 外观性状 | Solution | Yellow-green or gray |
| 储存条件 | 储存在干爽的惰性气体下，保持容器密封，储存在阴凉，干燥的地方 |
| 稳定性 | 常温常压下稳定，避免氧化物 酒精 酸接触 |
| 计算化学 | 1、 氢键供体数量：0 2、 氢键受体数量：2 3、 可旋转化学键数量：0 4、 拓扑分子极性表面积（TPSA）：0 5、 重原子数量：5 6、 表面电荷：0 7、 复杂度：14.4 8、 同位素原子数量：0 9、 确定原子立构中心数量：0 10、 不确定原子立构中心数量：0 11、 确定化学键立构中心数量：0 12、 不确定化学键立构中心数量：0 13、 共价键单元数量：3 |
| 更多 | 1. 性状：未确定。 2. 密度（g/mL,25/4℃）： 0.851 3. 相对蒸汽密度（g/mL,空气=1）：未确定 4. 熔点（ºC）：未确定 5. 沸点（ºC,常压）：未确定 6. 沸点（ºC,5.2kPa）： 未确定 7. 折射率： 未确定 8. 闪点（ºC）： -40 9. 比旋光度（º）： 未确定 10. 自燃点或引燃温度（ºC）： 未确定 11. 蒸气压（kPa,25ºC）： 未确定 12. 饱和蒸气压（kPa,60ºC）： 未确定 13. 燃烧热（KJ/mol）：未确定 14. 临界温度（ºC）： 未确定 15. 临界压力（KPa）： 未确定 16. 油水（辛醇/水）分配系数的对数值： 未确定 17. 爆炸上限（%,V/V）：未确定 18. 爆炸下限（%,V/V）： 未确定 19. 溶解性：未确定 |
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SECTION 1: Identification of the substance/mixture and of the company/undertaking Product identifiers Product name: Allylmagnesium bromide solution REACH No.: A registration number is not available for this substance as the substance or its uses are exempted from registration, the annual tonnage does not require a registration or the registration is envisaged for a later registration deadline.
Relevant identified uses of the substance or mixture and uses advised against Identified uses: Laboratory chemicals, Manufacture of substances SECTION 2: Hazards identification Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Flammable liquids (Category 2), H225 Pyrophoric liquids (Category 1), H250 Substances, which in contact with water, emit flammable gases (Category 1), H260 Acute toxicity, Oral (Category 4), H302 Skin corrosion (Category 1B), H314 Specific target organ toxicity - single exposure (Category 3), H336 For the full text of the H-Statements mentioned in this Section, see Section 16. Classification according to EU Directives 67/548/EEC or 1999/45/EC F Highly flammableR11, R15 C CorrosiveR34 Xn HarmfulR22 R19, R67, R14 For the full text of the R-phrases mentioned in this Section, see Section 16. Label elements Labelling according Regulation (EC) No 1272/2008 Pictogram Signal wordDanger Hazard statement(s) H225Highly flammable liquid and vapour. H250Catches fire spontaneously if exposed to air. H260In contact with water releases flammable gases which may ignite spontaneously. H302Harmful if swallowed. H314Causes severe skin burns and eye damage. H336May cause drowsiness or dizziness. Precautionary statement(s) P210Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P222Do not allow contact with air. P223Keep away from any possible contact with water, because of violent reaction and possible flash fire. P231 + P232Handle under inert gas. Protect from moisture. P370 + P378In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. P422Store contents under inert gas. Supplemental Hazard information (EU) EUH014Reacts violently with water. EUH019May form explosive peroxides. According to European Directive 67/548/EEC as amended. Hazard symbol(s)F Highly flammable C Corrosive R-phrase(s) R11Highly flammable. R14/15Reacts violently with water, liberating extremely flammable gases. R19May form explosive peroxides. R22Harmful if swallowed. R34Causes burns. R67Vapours may cause drowsiness and dizziness. S-phrase(s) S16Keep away from sources of ignition - No smoking. S26In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39Wear suitable protective clothing, gloves and eye/face protection. S43In case of fire, use sand, dry chemical or alcohol-resistant foam. S45In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Other hazards - none SECTION 3: Composition/information on ingredients Mixtures Formula: C3H5BrMg Molecular Weight: 145,28 g/mol Hazardous ingredients according to Regulation (EC) No 1272/2008 ComponentClassificationConcentration Diethyl ether CAS-No.60-29-7Flam. Liq. 1; Acute Tox. 4; Eye 50 - 100 % EC-No.200-467-2Irrit. 2; STOT SE 3; H224, Index-No.603-022-00-4H302, H319, H336, EUH019, EUH066 Allylmagnesium bromide CAS-No.1730-25-2Pyr. Liq. 1; Water-react. 1;10 - 20 % EC-No.217-046-4Skin Corr. 1B; H260, H314, H250, H260, H314, EUH014 Hazardous ingredients according to Directive 1999/45/EC ComponentClassificationConcentration Diethyl ether CAS-No.60-29-7F+, Xn, R12 - R19 - R22 - R66 50 - 100 % EC-No.200-467-2- R67 Index-No.603-022-00-4 Allylmagnesium bromide CAS-No.1730-25-2F, R14/15 - R3410 - 20 % EC-No.217-046-4 For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 16 SECTION 4: First aid measures Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 Indication of any immediate medical attention and special treatment needed no data available SECTION 5: Firefighting measures Extinguishing media Suitable extinguishing media Dry powder Special hazards arising from the substance or mixture no data available Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. Further information no data available SECTION 6: Accidental release measures Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. For personal protection see section 8. Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Methods and materials for containment and cleaning up Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13). Do not flush with water. Reference to other sections For disposal see section 13. SECTION 7: Handling and storage Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge. For precautions see section 2.2. Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Never allow product to get in contact with water during storage. Handle and store under inert gas. Specific end use(s) A part from the uses mentioned in section 1.2 no other specific uses are stipulated SECTION 8: Exposure controls/personal protection Control parameters Components with workplace control parameters Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Body Protection Complete suit protecting against chemicals, Flame retardant antistatic protective clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of environmental exposure Prevent further leakage or spillage if safe to do so. Do not let product enter drains. SECTION 9: Physical and chemical properties Information on basic physical and chemical properties a) AppearanceForm: clear, liquid Colour: light brown b) Odourno data available c) Odour Thresholdno data available d) pHno data available e) Melting point/freezingno data available point f) Initial boiling point and no data available boiling range g) Flash point-40 °C - closed cup h) Evapouration rateno data available i) Flammability (solid, gas) no data available j) Upper/lowerno data available flammability or explosive limits k) Vapour pressureno data available l) Vapour densityno data available m) Relative density0,851 g/cm3 at 25 °C n) Water solubilityno data available o) Partition coefficient: n- no data available octanol/water p) Auto-ignitionno data available temperature q) Decompositionno data available temperature r) Viscosityno data available s) Explosive propertiesno data available t) Oxidizing propertiesno data available Other safety information no data available SECTION 10: Stability and reactivity Reactivity no data available Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions Reacts violently with water. Conditions to avoid Heat, flames and sparks. Extremes of temperature and direct sunlight. Exposure to moisture. Incompatible materials Oxidizing agents, Strong acids Hazardous decomposition products Other decomposition products - no data available In the event of fire: see section 5 SECTION 11: Toxicological information Information on toxicological effects Acute toxicity no data available Skin corrosion/irritation no data available Serious eye damage/eye irritation no data available Respiratory or skin sensitisation no data available Germ cell mutagenicity no data available Carcinogenicity IARC:No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity no data available Specific target organ toxicity - single exposure no data available Specific target organ toxicity - repeated exposure no data available Aspiration hazard no data available Additional Information RTECS: Not available Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi, pneumonitis, pulmonary edema, burning sensation, Cough, wheezing, laryngitis, Shortness of breath, Headache, Nausea Liver - Irregularities - Based on Human Evidence (Diethyl ether) SECTION 12: Ecological information Toxicity no data available Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil no data available Results of PBT and vPvB assessment PBT/vPvB assessment not available as chemical safety assessment not required/not conducted Other adverse effects no data available SECTION 13: Disposal considerations Waste treatment methods Product Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product. SECTION 14: Transport information UN number ADR/RID: 3399IMDG: 3399IATA: 3399 UN proper shipping name ADR/RID: ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE (Diethyl ether, Allylmagnesium bromide) IMDG: ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE (Diethyl ether, Allylmagnesium bromide) IATA:Organometallic substance, liquid, water-reactive, flammable (Diethyl ether, Allylmagnesium bromide) Transport hazard class(es) ADR/RID: 4.3 (3)IMDG: 4.3 (3)IATA: 4.3 (3) Packaging group ADR/RID: IIMDG: IIATA: I Environmental hazards ADR/RID: noIMDG Marine pollutant: noIATA: no Special precautions for user no data available SECTION 15 - REGULATORY INFORMATION N/A SECTION 16 - ADDITIONAL INFORMATION N/A |
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毒理学数据: 对眼睛、皮肤、粘膜有刺激作用
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| 危害码 (欧洲) | F+: Highly flammable;C: Corrosive; |
|---|---|
| 风险声明 (欧洲) | R12;R14/15;R19;R22;R34;R66;R67 |
| 安全声明 (欧洲) | 9-16-29-33-43-45 |
| 危险品运输编码 | UN 3399 |
| WGK德国 | 1 |
| 包装等级 | III |
| 海关编码 | 2931900090 |
|
~92%
1730-25-2 |
| 文献：EP1669398 B1, ; Page/Page column ; |
|
~%
1730-25-2 |
| 文献：Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), , p. 464 - 467 |
|
~0%
1730-25-2 |
| 文献：Tetrahedron Letters, , vol. 23, # 14 p. 1497 - 1500 |
|
~%
1730-25-2 |
| 文献：Tetrahedron Letters, , vol. 23, # 14 p. 1497 - 1500 |
| 海关编码 | 2931900090 |
|---|---|
| 中文概述 | 2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0% |
| Summary | 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0% |
