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| 中文名 | 2-氟丙烯酸甲酯 |
|---|---|
| 英文名 | methyl 2-fluoroprop-2-enoate |
| 中文别名 |
Alpha-氟丙烯酸甲酯
2-氟代丙烯酸甲酯 |
| 英文别名 |
Methyl 2-fluoroacrylate
2-Propenoic acid, 2-fluoro-, methyl ester methyl 2-fluoro-2-propenoate 2-fluoro-acrylic acid methyl ester Methyl fluoroacrylate 2-Fluor-acrylsaeure-methylester |
| 密度 | 1.1±0.1 g/cm3 |
|---|---|
| 沸点 | 75.9±15.0 °C at 760 mmHg |
| 分子式 | C4H5FO2 |
| 分子量 | 104.080 |
| 闪点 | 1.1±15.3 °C |
| 精确质量 | 104.027359 |
| PSA | 26.30000 |
| LogP | 0.68 |
| 外观性状 | Liquid |
| 蒸汽压 | 103.0±0.1 mmHg at 25°C |
| 折射率 | 1.367 |
| 储存条件 | 0-10°C;避免加热 |
| 水溶解性 | Slightly soluble in water. |
|
Material Safety Data Sheet
Section1. Identification of the substance Product Name: Methyl 2-fluoroacrylate, BHT stablized Synonyms: Section2. Hazards identification Harmful by inhalation, in contact with skin, and if swallowed. H224:Extremely flammable liquid and vapour
H301:Toxic if swallowed H315:Causes skin irritation H319:Causes serious eye irritation H335:May cause respiratory irritation P210:Keep away from heat/sparks/open flames/hot surfaces. No smoking P301+P310:IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician P303+P361+P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing P405:Store locked up Section3. Composition/information on ingredients. Ingredient name:Methyl 2-fluoroacrylate, BHT stablized CAS number:2343-89-7 Section4. First aid measures Skin contact:Immediately wash skin with copious amounts of water for at least 15 minutes while removing contaminated clothing and shoes. If irritation persists, seek medical attention. Eye contact:Immediately wash skin with copious amounts of water for at least 15 minutes. Assure adequate flushing of the eyes by separating the eyelids with fingers. If irritation persists, seek medical attention. Inhalation:Remove to fresh air. In severe cases or if symptoms persist, seek medical attention. Ingestion:Wash out mouth with copious amounts of water for at least 15 minutes. Seek medical attention. Section5. Fire fighting measures In the event of a fire involving this material, alone or in combination with other materials, use dry powder or carbon dioxide extinguishers. Protective clothing and self-contained breathing apparatus should be worn. Section6. Accidental release measures Personal precautions: Wear suitable personal protective equipment which performs satisfactorily and meets local/state/national standards. Respiratory precaution:Wear approved mask/respirator Hand precaution:Wear suitable gloves/gauntlets Skin protection:Wear suitable protective clothing Eye protection:Wear suitable eye protection Methods for cleaning up: Mix with sand or similar inert absorbent material, sweep up and keep in a tightly closed container for disposal. See section 12. Environmental precautions: Do not allow material to enter drains or water courses. Section7. Handling and storage Handling:This product should be handled only by, or under the close supervision of, those properly qualified in the handling and use of potentially hazardous chemicals, who should take into account the fire, health and chemical hazard data given on this sheet. Storage:Store in closed vessels, refrigerated. Section8. Exposure Controls / Personal protection Engineering Controls: Use only in a chemical fume hood. Personal protective equipment: Wear laboratory clothing, chemical-resistant gloves and safety goggles. General hydiene measures: Wash thoroughly after handling. Wash contaminated clothing before reuse. Section9. Physical and chemical properties Not specified Appearance: Boiling point:No data Melting point:No data Flash point:No data Density:No data Molecular formula: C4H5FO2 Molecular weight: 104.1 Section10. Stability and reactivity Conditions to avoid: Heat, flames and sparks. Materials to avoid: Oxidizing agents. Possible hazardous combustion products: Carbon monoxide, hydrogen fluoride. Section11. Toxicological information No data. Section12. Ecological information No data. Section13. Disposal consideration Arrange disposal as special waste, by licensed disposal company, in consultation with local waste disposal authority, in accordance with national and regional regulations. Section14. Transportation information UN Number:UN1993Class: 3Packing group: II Proper shipping name: FLAMMABLE LIQUIDS, N.O.S. (Methyl 2-fluoroacrylate, BHT stablized) Section15. Regulatory information No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302, or have known CAS numbers that exceed the threshold reporting levels established by SARA Title III, Section 313. SECTION 16 - ADDITIONAL INFORMATION N/A |
| 危害码 (欧洲) | Xi: Irritant; |
|---|---|
| 风险声明 (欧洲) | R10 |
| 安全声明 (欧洲) | 16-26-36 |
| 危险品运输编码 | UN 1993 |
| 包装等级 | Ⅱ |
| 海关编码 | 2916190090 |
|
~93%
2343-89-7 |
| 文献：SALTIGO GMBH Patent: US2012/283468 A1, 2012 ; Location in patent: Page/Page column 5 ; |
|
~58%
2343-89-7 |
| 文献：DSM IP ASSETS B.V.; DSM FINE CHEMICALS AUSTRIA NFG. GMBH and CO KG; KAPITAN, Peter; SAJTOS, Alexander Patent: WO2014/1365 A1, 2014 ; Location in patent: Page/Page column 7-8 ; |
|
~82%
2343-89-7 |
| 文献：Boguslavskaya, L. S.; Chuvatkin, N.; Morozova, T. V.; Panteleeva, I. Yu.; Kartashov, A. V.; Sineokov, A. P. Journal of Organic Chemistry USSR (English Translation), 1987 , p. 1060 - 1064 Zhurnal Organicheskoi Khimii, 1987 , vol. 23, # 6 p. 1173 - 1177 |
|
~74%
2343-89-7 |
| 文献：Majumdar, Ramendra N.; Harwood, H. James Synthetic Communications, 1981 , vol. 11, # 11 p. 901 - 908 |
|
~97%
2343-89-7 |
| 文献：Tolman, Vladimir; Spronglova, Pavla Collection of Czechoslovak Chemical Communications, 1983 , vol. 48, # 1 p. 319 - 326 |
|
~10%
2343-89-7 |
| 文献：Journal of Organic Chemistry USSR (English Translation), , p. 1392 - 1397 Zhurnal Organicheskoi Khimii, , vol. 16, # 8 p. 1640 - 1645 |
|
~9%
2343-89-7 |
| 文献：Journal of Organic Chemistry USSR (English Translation), , p. 1392 - 1397 Zhurnal Organicheskoi Khimii, , vol. 16, # 8 p. 1640 - 1645 |
|
~50%
2343-89-7 |
| 文献：Gassen, K.-R.; Bielefeldt, D.; Marhold, A.; Andres P. Journal of Fluorine Chemistry, 1991 , vol. 55, # 2 p. 149 - 162 |
|
~%
2343-89-7 |
| 文献：Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques, , vol. 282, p. 1129 - 1131 |
| 上游产品 10 | |
|---|---|
| 下游产品 0 | |
| 海关编码 | 2916190090 |
|---|---|
| 中文概述 | 2916190090 其他不饱和无环一元羧酸（包括其酸酐、酰卤化物，过氧化物和过氧酸以及它们的衍生物）。监管条件:AB(入境货物通关单,出境货物通关单)。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0% |
| 申报要素 | 品名, 成分含量, 用途, 丙烯酸、丙烯酸盐或酯应报明包装 |
| 监管条件 | A.入境货物通关单 B.出境货物通关单 |
| 检验检疫 | R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验 |
| Summary | 2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0% |
