Methyl 2-fluoroacrylate

Modify Date: 2024-01-02 16:18:58

Methyl 2-fluoroacrylate Structure
Methyl 2-fluoroacrylate structure
Common Name Methyl 2-fluoroacrylate
CAS Number 2343-89-7 Molecular Weight 104.080
Density 1.1±0.1 g/cm3 Boiling Point 75.9±15.0 °C at 760 mmHg
Molecular Formula C4H5FO2 Melting Point N/A
MSDS N/A Flash Point 1.1±15.3 °C

 Names

Name methyl 2-fluoroprop-2-enoate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.1±0.1 g/cm3
Boiling Point 75.9±15.0 °C at 760 mmHg
Molecular Formula C4H5FO2
Molecular Weight 104.080
Flash Point 1.1±15.3 °C
Exact Mass 104.027359
PSA 26.30000
LogP 0.68
Appearance of Characters Liquid
Vapour Pressure 103.0±0.1 mmHg at 25°C
Index of Refraction 1.367
Water Solubility Slightly soluble in water.

 MSDS

Material Safety Data Sheet

Section1. Identification of the substance
Product Name: Methyl 2-fluoroacrylate, BHT stablized
Synonyms:

Section2. Hazards identification
Harmful by inhalation, in contact with skin, and if swallowed.
H224:Extremely flammable liquid and vapour
H301:Toxic if swallowed
H315:Causes skin irritation
H319:Causes serious eye irritation
H335:May cause respiratory irritation
P210:Keep away from heat/sparks/open flames/hot surfaces. No smoking
P301+P310:IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P303+P361+P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present
and easy to do – continue rinsing
P405:Store locked up

Section3. Composition/information on ingredients.
Ingredient name:Methyl 2-fluoroacrylate, BHT stablized
CAS number:2343-89-7

Section4. First aid measures
Skin contact:Immediately wash skin with copious amounts of water for at least 15 minutes while removing
contaminated clothing and shoes. If irritation persists, seek medical attention.
Eye contact:Immediately wash skin with copious amounts of water for at least 15 minutes. Assure adequate
flushing of the eyes by separating the eyelids with fingers. If irritation persists, seek medical
attention.
Inhalation:Remove to fresh air. In severe cases or if symptoms persist, seek medical attention.
Ingestion:Wash out mouth with copious amounts of water for at least 15 minutes. Seek medical attention.

Section5. Fire fighting measures
In the event of a fire involving this material, alone or in combination with other materials, use dry
powder or carbon dioxide extinguishers. Protective clothing and self-contained breathing apparatus
should be worn.

Section6. Accidental release measures
Personal precautions: Wear suitable personal protective equipment which performs satisfactorily and meets local/state/national
standards.
Respiratory precaution:Wear approved mask/respirator
Hand precaution:Wear suitable gloves/gauntlets
Skin protection:Wear suitable protective clothing
Eye protection:Wear suitable eye protection
Methods for cleaning up: Mix with sand or similar inert absorbent material, sweep up and keep in a tightly closed container
for disposal. See section 12.
Environmental precautions: Do not allow material to enter drains or water courses.

Section7. Handling and storage
Handling:This product should be handled only by, or under the close supervision of, those properly qualified
in the handling and use of potentially hazardous chemicals, who should take into account the fire,
health and chemical hazard data given on this sheet.
Storage:Store in closed vessels, refrigerated.

Section8. Exposure Controls / Personal protection
Engineering Controls: Use only in a chemical fume hood.
Personal protective equipment: Wear laboratory clothing, chemical-resistant gloves and safety goggles.
General hydiene measures: Wash thoroughly after handling. Wash contaminated clothing before reuse.

Section9. Physical and chemical properties
Not specified
Appearance:
Boiling point:No data
Melting point:No data
Flash point:No data
Density:No data
Molecular formula: C4H5FO2
Molecular weight: 104.1

Section10. Stability and reactivity
Conditions to avoid: Heat, flames and sparks.
Materials to avoid: Oxidizing agents.
Possible hazardous combustion products: Carbon monoxide, hydrogen fluoride.

Section11. Toxicological information
No data.

Section12. Ecological information
No data.

Section13. Disposal consideration
Arrange disposal as special waste, by licensed disposal company, in consultation with local waste
disposal authority, in accordance with national and regional regulations.

Section14. Transportation information
UN Number:UN1993Class: 3Packing group: II
Proper shipping name: FLAMMABLE LIQUIDS, N.O.S. (Methyl 2-fluoroacrylate, BHT stablized)

Section15. Regulatory information
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section
302, or have known CAS numbers that exceed the threshold reporting levels established by SARA
Title III, Section 313.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xi: Irritant;
Risk Phrases R10
Safety Phrases 16-26-36
RIDADR UN 1993
Packaging Group
HS Code 2916190090

 Synthetic Route

~93%

Methyl 2-fluoroacrylate Structure

Methyl 2-fluoro...

CAS#:2343-89-7

Literature: SALTIGO GMBH Patent: US2012/283468 A1, 2012 ; Location in patent: Page/Page column 5 ;

~58%

Methyl 2-fluoroacrylate Structure

Methyl 2-fluoro...

CAS#:2343-89-7

Literature: DSM IP ASSETS B.V.; DSM FINE CHEMICALS AUSTRIA NFG. GMBH and CO KG; KAPITAN, Peter; SAJTOS, Alexander Patent: WO2014/1365 A1, 2014 ; Location in patent: Page/Page column 7-8 ;

~82%

Methyl 2-fluoroacrylate Structure

Methyl 2-fluoro...

CAS#:2343-89-7

Literature: Boguslavskaya, L. S.; Chuvatkin, N.; Morozova, T. V.; Panteleeva, I. Yu.; Kartashov, A. V.; Sineokov, A. P. Journal of Organic Chemistry USSR (English Translation), 1987 , p. 1060 - 1064 Zhurnal Organicheskoi Khimii, 1987 , vol. 23, # 6 p. 1173 - 1177

~74%

Methyl 2-fluoroacrylate Structure

Methyl 2-fluoro...

CAS#:2343-89-7

Literature: Majumdar, Ramendra N.; Harwood, H. James Synthetic Communications, 1981 , vol. 11, # 11 p. 901 - 908

~97%

Methyl 2-fluoroacrylate Structure

Methyl 2-fluoro...

CAS#:2343-89-7

Literature: Tolman, Vladimir; Spronglova, Pavla Collection of Czechoslovak Chemical Communications, 1983 , vol. 48, # 1 p. 319 - 326

~10%

Methyl 2-fluoroacrylate Structure

Methyl 2-fluoro...

CAS#:2343-89-7

Literature: Journal of Organic Chemistry USSR (English Translation), , p. 1392 - 1397 Zhurnal Organicheskoi Khimii, , vol. 16, # 8 p. 1640 - 1645

~9%

Methyl 2-fluoroacrylate Structure

Methyl 2-fluoro...

CAS#:2343-89-7

Literature: Journal of Organic Chemistry USSR (English Translation), , p. 1392 - 1397 Zhurnal Organicheskoi Khimii, , vol. 16, # 8 p. 1640 - 1645

~50%

Methyl 2-fluoroacrylate Structure

Methyl 2-fluoro...

CAS#:2343-89-7

Literature: Gassen, K.-R.; Bielefeldt, D.; Marhold, A.; Andres P. Journal of Fluorine Chemistry, 1991 , vol. 55, # 2 p. 149 - 162

~%

Methyl 2-fluoroacrylate Structure

Methyl 2-fluoro...

CAS#:2343-89-7

Literature: Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques, , vol. 282, p. 1129 - 1131

 Customs

HS Code 2916190090
Summary 2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

 Synonyms

Methyl 2-fluoroacrylate
2-Propenoic acid, 2-fluoro-, methyl ester
methyl 2-fluoro-2-propenoate
2-fluoro-acrylic acid methyl ester
Methyl fluoroacrylate
2-Fluor-acrylsaeure-methylester
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