二环己胺

二环己胺用途

【用途一】
用于有机合成，也用作杀虫剂、酸性气体吸收剂和钢铁防锈剂
【用途二】
用于制造橡胶硫化促进剂、杀虫剂、催化剂、防腐剂等
【用途三】
广泛用作有机合成中间体，可用于制取染料中间体、橡胶促进剂、硝化纤维漆、杀虫剂、催化剂、防腐剂、气相缓蚀剂及燃料抗氧化添加剂等。也用作萃取剂。二环己胺的脂肪酸盐和硫酸盐具有肥皂的去污性能，用于印染和纺织工业。其金属络合物用作油墨、油漆的催化剂。

二环己胺名称

[ CAS 号 ]:
101-83-7

[ 中文名 ]:
十二氢二苯胺

[ 英文名 ]:
Dicyclohexylamine

[中文别名 ]:

二环己胺

[英文别名 ]:

biscyclohexylamine
EINECS 202-980-7
Dicyklohexylamin
N-Cyclohexyl-cyclohexylamine
Dicyclohexylamine
Bis(Cyclohexyl)Amine
DCHA
N-Cyclohexylcyclohexanamine
Dicyclohexylamine (DCHA)
MFCD00011658

二环己胺物理化学性质

[ 密度 ]:
0.9±0.1 g/cm3

[ 沸点 ]:
256.1±8.0 °C at 760 mmHg

[ 熔点 ]:
-2 °C

[ 分子式 ]:
C₁₂H₂₃N

[ 分子量 ]:
181.318

[ 闪点 ]:
96.1±0.0 °C

[ 精确质量 ]:
181.183044

[ PSA ]:
12.03000

[ LogP ]:
3.69

[ 外观性状 ]:
透明至黄色液体

[ 蒸汽密度 ]:
6 (vs air)

[ 蒸汽压 ]:
0.0±0.5 mmHg at 25°C

[ 折射率 ]:
1.488

[ 储存条件 ]:
库房通风低温干燥,与酸类分开存放

[ 稳定性 ]:
Stable. Incompatible with strong acids, strong oxidizing agents.

[ 水溶解性 ]:
1 g/L (20 ºC)

[ 凝固点 ]:
-2℃

二环己胺MSDS

二环己胺毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: HY4025000

CHEMICAL NAME :: Dicyclohexylamine

CAS REGISTRY NUMBER :: 101-83-7

BEILSTEIN REFERENCE NO. :: 0605923

LAST UPDATED :: 199710

DATA ITEMS CITED :: 18

MOLECULAR FORMULA :: C12-H23-N

MOLECULAR WEIGHT :: 181.36

WISWESSER LINE NOTATION :: L6TJ AM- AL6TJ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 373 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 135 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 500 mg/kg

TOXIC EFFECTS :: Behavioral - convulsions or effect on seizure threshold

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 40 gm/kg/52W-I

TOXIC EFFECTS :: Tumorigenic - equivocal tumorigenic agent by RTECS criteria Gastrointestinal - tumors Liver - tumors

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 2404 mg/kg/48W-I

TOXIC EFFECTS :: Tumorigenic - equivocal tumorigenic agent by RTECS criteria Tumorigenic - tumors at site of application

MUTATION DATA

TYPE OF TEST :: Cytogenetic analysis

TEST SYSTEM :: Human Leukocyte

DOSE/DURATION :: 200 ug/L

REFERENCE :: INHEAO Industrial Health. (National Institute of Industrial Health, 6-21-1 Nagao, Tama-ku, Kawasaki, 213 Japan) V.1- 1963- Volume(issue)/page/year: 9,188,1971 *** REVIEWS *** IARC Cancer Review:Animal Limited Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 22,55,1980 IARC Cancer Review:Human Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 22,55,1980 IARC Cancer Review:Group 3 IMSUDL IARC Monographs, Supplement. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) No.1- 1979- Volume(issue)/page/year: 7,178,1987 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 1 mg/m3;Skin JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M1151 No. of Facilities: 60 (estimated) No. of Industries: 3 No. of Occupations: 3 No. of Employees: 368 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M1151 No. of Facilities: 40 (estimated) No. of Industries: 2 No. of Occupations: 3 No. of Employees: 3412 (estimated) No. of Female Employees: 169 (estimated)

二环己胺安全信息

[ 符号 ]:

GHS05, GHS06, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H301 + H311-H314-H410

[ 警示性声明 ]:
P273-P280-P301 + P310 + P330-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
C:Corrosive;N:Dangerousfortheenvironment;

[ 风险声明 (欧洲) ]:
R22;R34;R50/53

[ 安全声明 (欧洲) ]:
S26-S36/37/39-S45-S60-S61

[ 危险品运输编码 ]:
UN 2565 8/PG 3

[ WGK德国 ]:
2

[ RTECS号 ]:
HY4025000

[ 包装等级 ]:
III

[ 危险类别 ]:
8

[ 海关编码 ]:
2921300090

二环己胺合成路线

二环己胺上下游产品

二环己胺上游产品

二环己胺下游产品

二环己胺制备

以苯胺为原料，在催化剂存在下，高温高压加氢，制得二环己胺。

精制方法：分馏精制。

二环己胺海关

[ 海关编码 ]: 2921300090

[ 中文概述 ]:
2921300090 其他环（烷，烯，萜烯）单胺或多胺（包括其衍生物及它们的盐）. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2921300090 other cyclanic, cyclenic or cyclotherpenic mono- or polyamines, and their derivatives; salts thereof。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

二环己胺文献

Evaluation of quadrupole-time-of-flight mass spectrometry in comprehensive two-dimensional gas chromatography.

J. Chromatogr. A. 1362 , 262-9, (2014)

Quadrupole time-of-flight mass spectrometry (Q-TOFMS) has been evaluated with respect to its applicability in comprehensive two-dimensional gas chromatography (GC×GC). At a maximum acquisition frequen...

Synthesis and application of ionic liquid matrices (ILMs) for effective pathogenic bacteria analysis in matrix assisted laser desorption/ionization (MALDI-MS).

Anal. Chim. Acta 767 , 104-11, (2013)

Application of two new series of ionic liquid matrices (ILMs) based on the two most predominantly used conventional organic matrices (Sinapinic acid and 2,5-DHB) in conjugation with various bases (ani...

Retention time prediction of compounds in Grob standard mixture for apolar capillary columns in temperature-programmed gas chromatography.

Anal. Bioanal. Chem 393(1) , 327-34, (2009)

This paper presents an extension of a previous investigation in which the behavior of nonpolar compounds in temperature-programmed gas chromatographic runs was predicted using thermodynamic (entropy a...

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