Journal of the American Chemical Society

Mechanistic investigation of the cobalt-catalyzed selective conversion of diallylanilines to quinolines involving CN and CH activations

L Li, WD Jones

文献索引：Li, Ng; Jones, William D. Journal of the American Chemical Society, 2007 , vol. 129, # 35 p. 10707 - 10713

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被引用次数: 55

摘要

2, 3-Substituted quinolines were readily prepared from diallylanilines in good yields under mild conditions by using Co2 (CO) 8 as catalyst. 1, 2 Regioselectivity has been explored by examining a series of electron-donating and electron-withdrawing functional groups at ortho, meta, and para positions of the diallylanilines. The results show that both steric and electronic effects influence the isolated yields. Electron-withdrawing groups inhibit the ...