Ruthenium??Catalyzed synthesis of quinolines from anilines and N??allylic compounds by cascade amine exchange reaction??heteroannulation

CS Cho, B Ho Oh, SC Shim…

文献索引：Chan Sik Cho; Byoung Ho Oh; Sang Chul Shim; Dae Hee Oh Journal of Heterocyclic Chemistry, 2000 , vol. 37, # 5 p. 1315 - 1320

全文：HTML全文

被引用次数: 18

摘要

Abstract Anilines react with N-allylic compounds such as triallylamine and N, N-diallylaniline in dioxane in the presence of a catalytic amount of ruthenium (III) chloride hydrate and bis (diphenylphosphino) methane and tin (II) chloride dihydrate to afford the corresponding quinolines in high yields. Several other phosphorus ligands are also effective, but bis (diphenylphosphino) methane is the ligand of choice. A reaction pathway involving ...