Canadian Journal of Chemistry

The sulfohaloform reaction. The stepwise conversion of dialkyl sulfides into alkanesulfonyl chlorides

JS Grossert, RF Langler

文献索引：Grossert,J.S.; Langler,R.F. Canadian Journal of Chemistry, 1977 , vol. 55, p. 407 - 420

被引用次数: 20

摘要

A thorough examination of the aqueous oxidative chlorination of 1, 3, 5-trithiane is described. The results are utilized to explore and delineate the scope of a general, stepwise, oxidative cleavage reaction of dialkyl sulfides in which they are successively halogenated and oxidized to α-polychlorosulfoxides; subsequently, these cleave to form sulfinyl chlorides, which hydrolyze and become further oxidized to yield alkanesulfonyl chlorides. The ...

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