Canadian Journal of Chemistry

The sulfohaloform reaction. The stepwise conversion of dialkyl sulfides into alkanesulfonyl chlorides

JS Grossert, RF Langler

Index: Grossert,J.S.; Langler,R.F. Canadian Journal of Chemistry, 1977 , vol. 55, p. 407 - 420

Full Text: HTML

Citation Number: 20

Abstract

A thorough examination of the aqueous oxidative chlorination of 1, 3, 5-trithiane is described. The results are utilized to explore and delineate the scope of a general, stepwise, oxidative cleavage reaction of dialkyl sulfides in which they are successively halogenated and oxidized to α-polychlorosulfoxides; subsequently, these cleave to form sulfinyl chlorides, which hydrolyze and become further oxidized to yield alkanesulfonyl chlorides. The ...

A simple and efficient preparation of sulfinyl chlorides fro...

[Youn, Joo-Hack; Herrmann, Rudolf Tetrahedron Letters, 1986 , vol. 27, # 13 p. 1493 - 1494]

S-Trifluoromethyl Sulfoximine as a Directing Group in Ortho-...

[Kowalczyk, Rafal; Edmunds, Andrew J. F.; Hall, Roger G.; Bolm, Carsten Organic Letters, 2011 , vol. 13, # 4 p. 768 - 771]

Sulfinyl and Sulfonyl Chlorides by Chlorination1, 2

[Douglass,I.B. et al. Journal of Organic Chemistry, 1961 , vol. 26, p. 1996 - 1999]

FTIR kinetic and mechanistic study of the atmospheric chemis...

[Patroescu, Iulia V.; Barnes, Ian; Becker, Karl H. Journal of Physical Chemistry, 1996 , vol. 100, # 43 p. 17207 - 17217]

Methylsulfur Trichloride1

[Brower; Douglass Journal of the American Chemical Society, 1951 , vol. 73, p. 5787]