Sulfinyl and Sulfonyl Chlorides by Chlorination1, 2

IB DOUGLASS, BS FARAH…

文献索引：Douglass,I.B. et al. Journal of Organic Chemistry, 1961 , vol. 26, p. 1996 - 1999

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被引用次数: 43

摘要

The critical factors in the preparation of alkanesulfinyl chlorides by the chlorination of mercaptans or disulfides in the presence of glacial acetic acid are discussed. This reaction has been extended to the preparation of alkanedisulfinyl chlorides and aromatic sulfinvl chlorides. Sulfinvl chlorides are converted to sulfonyl chlorides when treated with equimolar quantities of glacial acetic acid and chlorine.