FTIR kinetic and mechanistic study of the atmospheric chemistry of methyl thiolformate

IV Patroescu, I Barnes, KH Becker

文献索引：Patroescu, Iulia V.; Barnes, Ian; Becker, Karl H. Journal of Physical Chemistry, 1996 , vol. 100, # 43 p. 17207 - 17217

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被引用次数: 16

摘要

Some aspects of the atmospheric chemistry of methyl thiolformate (CH3SCHO), a recently detected intermediate in the oxidation of dimethyl sulfide, have been investigated at 298 K and 1000 mbar total pressure in large reaction chambers using long path in situ FTIR absorption spectroscopy for the analysis. Rate coefficients of (1.11±0.22)× 10-11 and (5.80±0.80)× 10-11 cm3 molecule-1 s-1 have been determined for its reaction with OH ...