Inert carbon free radicals. 2. Monofunctionalized tetradecachlorotriphenylmethyl radicals and related compounds

M Ballester, J Castaner, J Riera, A Ibanez…

文献索引：Ballester, M.; Castaner, J.; Riera, J.; Ibanez, A.; Pujadas, J. Journal of Organic Chemistry, 1982 , vol. 47, # 2 p. 259 - 264

全文：HTML全文

被引用次数: 47

摘要

Perchlorinated triphenylmethyl radicals, and their nonradical aH precursors, with hydrogen (2), carboxy (3), carbomethoxy (4), ammonium carboxylate (51, bromo (6), iodo (7), and methyl (8) substituents in the 4-position have been synthesized and their reactivities studied. The radicals are completely disassociated even in the solid (magnetic susceptibility), and their radical character is not changed by O2 or highly reactive chemical agents. Their ...