Inert carbon free radicals. 10. Chlorination of perchlorotriphenylmethyl (PTM) radical. Synthesis, structure, and reactivity of perchloro (diphenylmethylene) cyclohexa-1, …

…, J Castañer, C Carreras, JJ Ubierna…

文献索引：Ballester, M.; Riera, J.; Castaner, J.; Carreras, C.; Ubierna, J. J.; et al. Journal of Organic Chemistry, 1989 , vol. 54, # 19 p. 4611 - 4615

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被引用次数: 5

摘要

Perchlorotriphenylmethyl radical (PTM) is the paradigm of the chlorine-shielded" inert free radicals"(IF%), which owe their unique chemical inertia to the colossal overcrowding about their trivalent carbon. However, they are active in single electron-transfer processes. The present paper reports and describes a remarkable twc-step chlorination of PTM'consisting of a SET, giving the corresponding carbenium ion (PTM+), followed by chlorideion addition ...