Inert carbon free radicals. 2. Monofunctionalized tetradecachlorotriphenylmethyl radicals and related compounds

M Ballester, J Castaner, J Riera, A Ibanez…

Index: Ballester, M.; Castaner, J.; Riera, J.; Ibanez, A.; Pujadas, J. Journal of Organic Chemistry, 1982 , vol. 47, # 2 p. 259 - 264

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Citation Number: 47

Abstract

Perchlorinated triphenylmethyl radicals, and their nonradical aH precursors, with hydrogen (2), carboxy (3), carbomethoxy (4), ammonium carboxylate (51, bromo (6), iodo (7), and methyl (8) substituents in the 4-position have been synthesized and their reactivities studied. The radicals are completely disassociated even in the solid (magnetic susceptibility), and their radical character is not changed by O2 or highly reactive chemical agents. Their ...