Unique single-electron transfers between chemically inert triphenylmethyl radicals and triphenylmethyl anions

M Ballester, I Pascual, J Torres

文献索引：Ballester, Manuel; Pascual, Isabel; Torres, Josep Journal of Organic Chemistry, 1990 , vol. 55, p. 3035 - 3044

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被引用次数: 14

摘要

A number of SET reactions between inert 4-X-tetradecachlorotriphenylmethyl radicals (X- PTM') and stable tetra-n-butylammonium (Q+) 4-Y-tetradecachlorotriphenylmethides (Q+ Y- PTM:-; X, Yh, Me, NH, CO, Me2NC0, Ph, NCO, MeOCO, PhOCO, NH,, MeO, C1, Br,-0CO) have been studied in THF, at room temperature, by the ESR technique. These processes are abnormally slow, since no significant ESR linewidth and/or hyperfine coupling changes ...