1,1'-二叔丁基二磷烷
1,1'-二叔丁基二磷烷结构式
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常用名 | 1,1'-二叔丁基二磷烷 | 英文名 | (S,S',R,R')-Tangphos |
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| CAS号 | 470480-32-1 | 分子量 | 286.37300 | |
| 密度 | N/A | 沸点 | 353.584ºC at 760 mmHg | |
| 分子式 | C16H32P2 | 熔点 | 60-65ºC | |
| MSDS | 中文版 美版 | 闪点 | 176.043ºC |
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Highly efficient synthesis of chiral beta-amino acid derivatives via asymmetric hydrogenation.
Org. Lett. 4 , 4159, (2002) The Rh-TangPhos complex is an efficient hydrogenation catalyst for making chiral beta-amino acid derivatives. With the Rh-TangPhos system, high enantioselectivities (up to 99.6%) and turnover numbers have been obtained in the hydrogenation of E/Z isomeric mix... |
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Asymmetric hydrogenation of itaconic acid and enol acetate derivatives with the Rh-TangPhos catalyst.
Org. Lett. 5 , 205, (2003) [reaction: see text] The Rh-TangPhos catalyst has been used for asymmetric hydrogenation of itaconic acid and enol acetate derivatives. A variety of chiral 2-substituted succinic acids and chiral acetates have been obtained in excellent ee values (up to 99% e... |
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A chiral 1,2-bisphospholane ligand with a novel structural motif: applications in highly enantioselective Rh-catalyzed hydrogenations.
Angew. Chem. Int. Ed. Engl. 41 , 1612, (2002)
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Axtell, A. T. et al.
Organometallics 25 , 5003, (2006)
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