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1-三苯基膦烯-2-丙酮

1-三苯基膦烯-2-丙酮结构式
1-三苯基膦烯-2-丙酮结构式
品牌特惠专场
常用名 1-三苯基膦烯-2-丙酮 英文名 (Acetylmethylene)triphenylphosphorane
CAS号 1439-36-7 分子量 318.349
密度 1.1±0.1 g/cm3 沸点 478.5±28.0 °C at 760 mmHg
分子式 C21H19OP 熔点 203-205 °C(lit.)
MSDS 中文版 美版 闪点 243.2±24.0 °C

Cyclobutanones through SNi' ring closure, a mechanistic study.

J. Org. Chem. 72 , 2427, (2007)

Mechanistic studies on the intramolecular nucleophilic substitution with allylic rearrangement (SNi' reaction) and a new stereoselective access to substituted cyclobutanones are reported. 4,4-Dialkyl-5-oxohex-2E-en-1-yl methanesulfonates 4 were converted to 2...

Synthesis , 1359, (2007)