2-苯基-4-[(二苯基)(二苯基磷)甲基]-4,5-二氢-5-甲基氧唑铱
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2-苯基-4-[(二苯基)(二苯基磷)甲基]-4,5-二氢-5-甲基氧唑铱结构式
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常用名 | 2-苯基-4-[(二苯基)(二苯基磷)甲基]-4,5-二氢-5-甲基氧唑铱 | 英文名 | ((4s,5s)-(+)-o-[1-benzyl-1-(5-methyl-2-phenyl-4,5-dihydro-oxazol-4-yl)-2-phenylethyl]-diphenyl-phosphinite)(1,5-cod)iridium (i) tetrakis(3,5-bis(trifluoromethyl)phenylborate |
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| CAS号 | 405235-55-4 | 分子量 | 1719.25000 | |
| 密度 | N/A | 沸点 | N/A | |
| 分子式 | C77H58BF24IrNO2P | 熔点 | 112-113ºC | |
| MSDS | 美版 | 闪点 | N/A |
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A New Class of Modular Phosphinite-Oxazoline Ligands: Ir-Catalyzed Enantioselective Hydrogenation of Alkenes We thank Dr. Martin Studer and Dr. Beno_t Pugin (Solvias AG, Basel) for fruitful discussions, and Prof. Kevin Burgess (Texas A&M University) for preprints of related unpublished work. Financial support by the Swiss National Science Foundation is gratefully acknowledged.
Angew. Chem. Int. Ed. Engl. 40 , 4445-4447, (2001)
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Threonine-derived phosphinite-oxazoline ligands for the Ir-catalyzed enantioselective hydrogenation. Menges, F. and Pfaltz, A.
Adv. Synth. Catal. 344 , 40-44, (2002)
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