2-二叔丁基膦-3,4,5,6-四甲基-2′,4′,6′-三异丙基-1,1′-联苯
2-二叔丁基膦-3,4,5,6-四甲基-2′,4′,6′-三异丙基-1,1′-联苯结构式
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常用名 | 2-二叔丁基膦-3,4,5,6-四甲基-2′,4′,6′-三异丙基-1,1′-联苯 | 英文名 | Tetramethyl di-tBuXPhos |
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| CAS号 | 857356-94-6 | 分子量 | 480.748 | |
| 密度 | N/A | 沸点 | 534.1±50.0 °C at 760 mmHg | |
| 分子式 | C33H53P | 熔点 | 168-172ºC | |
| MSDS | 中文版 美版 | 闪点 | 294.4±36.4 °C |
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Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions employing dialkylbiaryl phosphine ligands.
Acc. Chem. Res. 41 , 1461, (2008) The cores of many types of polymers, ligands, natural products, and pharmaceuticals contain biaryl or substituted aromatic structures, and efficient methods of synthesizing these structures are crucial to the work of a broad spectrum of organic chemists. Rece... |
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Biaryl phosphane ligands in palladium-catalyzed amination.
Angew. Chem. Int. Ed. Engl. 47 , 6338, (2008) Palladium-catalyzed amination reactions of aryl halides have undergone rapid development in the last 12 years, largely driven by the implementation of new classes of ligands. Biaryl phosphanes have proven to provide especially active catalysts in this context... |
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Dialkylbiaryl Phosphines in Pd-Catalyzed Amination: A User's Guide.
Chem. Sci. 2 , 27, (2011) Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions and have been applied in a range of contexts. This review attempts to aid the reader in the selection of the best choice of reaction conditions and ligand of this cla... |
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Pd-catalyzed amidation of aryl chlorides using monodentate biaryl phosphine ligands: a kinetic, computational, and synthetic investigation.
J. Am. Chem. Soc. 129 , 13001, (2007) We present results on the amidation of aryl halides and sulfonates utilizing a monodentate biaryl phosphine-Pd catalyst. Our results are in accord with a previous report that suggests that the formation of kappa(2)-amidate complexes is deleterious to the effe... |