Boc-L-丙氨醛
Boc-L-丙氨醛结构式
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常用名 | Boc-L-丙氨醛 | 英文名 | Boc-L-alaninal |
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| CAS号 | 79069-50-4 | 分子量 | 173.210 | |
| 密度 | 1.0±0.1 g/cm3 | 沸点 | 248.5±23.0 °C at 760 mmHg | |
| 分子式 | C8H15NO3 | 熔点 | 89 °C | |
| MSDS | 美版 | 闪点 | 104.1±22.6 °C |
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Synthesis of the C(26)-C(32) Oxazole Fragment of Calyculin C: A Test Case for Oxazole Syntheses.
J. Org. Chem. 63 , 92-98, (1998) The synthesis of the C(26)-C(32) oxazole fragment 4 and its C(32) epimer 20 of serine/threonine protein phosphatase PP1 and PP2A inhibitor calyculin C is presented. The syn methyl arrangement in 4 was established through cyclic stereocontrol. Several methods ... |
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Synthesis of a C20-C26 segment of superstolide A by addition of a chiral allenylzinc reagent to (R)-N-boc alaninal.
Org. Lett. 7 , 1593-1596, (2005) [reaction: see text] Additions of chiral allenylzinc and indium reagents to N-Boc alaninal were examined as a possible route to a C20-C26 segment of superstolide A. Allenylzinc reagents, prepared in situ by palladiozincation of (R)- and (S)-5-pivalyloxy-3-but... |
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Practical syntheses of a CXCR3 antagonist.
J. Org. Chem. 76 , 1767-1774, (2011) Two new, reliable syntheses of a pyrido[2,3-d]-pyrimidine inhibitor of the CXCR3 receptor are described. A nine-step synthesis of the CXCR3 inhibitor (1) from 2-aminonicotinic acid was demonstrated on a multikilogram scale and incorporates a classic resolutio... |