![]() 2-(三异丙基甲硅烷基)-1,3-二噻烷结构式
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常用名 | 2-(三异丙基甲硅烷基)-1,3-二噻烷 | 英文名 | 1,3-dithian-2-yl-tri(propan-2-yl)silane |
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CAS号 | 145251-89-4 | 分子量 | 276.57700 | |
密度 | 0.854g/cm3 | 沸点 | 225.3ºC at 760 mmHg | |
分子式 | C13H28S2Si | 熔点 | 46-49ºC(lit.) | |
MSDS | 中文版 美版 | 闪点 | >230 °F |
Multicomponent linchpin couplings. Reaction of dithiane anions with terminal epoxides, epichlorohydrin, and vinyl epoxides: efficient, rapid, and stereocontrolled assembly of advanced fragments for complex molecule synthesis.
J. Am. Chem. Soc. 125 , 14435, (2003) The development, application, and advantages of a one-flask multicomponent dithiane linchpin coupling protocol, over the more conventional stepwise addition of dithiane anions to electrophiles leading to the rapid, efficient, and stereocontrolled assembly of ... |
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Smith, A. B., III; Boldi, A. M.
J. Am. Chem. Soc. 119 , 6925, (1997)
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