2-三甲基硅基-1,3-二噻烷
2-三甲基硅基-1,3-二噻烷结构式
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常用名 | 2-三甲基硅基-1,3-二噻烷 | 英文名 | 1,3-dithian-2-yl(trimethyl)silane |
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| CAS号 | 13411-42-2 | 分子量 | 192.417 | |
| 密度 | 1.0±0.1 g/cm3 | 沸点 | 261.7±0.0 °C at 760 mmHg | |
| 分子式 | C7H16S2Si | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | 96.1±0.0 °C |
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Multicomponent linchpin couplings. Reaction of dithiane anions with terminal epoxides, epichlorohydrin, and vinyl epoxides: efficient, rapid, and stereocontrolled assembly of advanced fragments for complex molecule synthesis.
J. Am. Chem. Soc. 125 , 14435, (2003) The development, application, and advantages of a one-flask multicomponent dithiane linchpin coupling protocol, over the more conventional stepwise addition of dithiane anions to electrophiles leading to the rapid, efficient, and stereocontrolled assembly of ... |
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Lewis base catalyzed 1,3-dithiane addition to carbonyl and imino compounds using 2-trimethylsilyl-1,3-dithiane.
Chem. Asian J. 3(8-9) , 1592-600, (2008) Lewis base-catalyzed 1,3-dithiane addition to electrophiles such as carbonyl compounds and N-substituted aldimines with 2-trimethylsilyl-1,3-dithiane (TMS-dithiane) is described. By the activation of the carbon-silicon bond in the presence of a Lewis base cat... |
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Smith, A. B., III; Boldi, A. M.
J. Am. Chem. Soc. 119 , 6925, (1997)
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Diazo transfer reaction of 2-(trimethylsilyl)-1, 3-dithiane with tosyl azide. Carbenic reactivity of transient 2-diazo-1, 3-dithiane. Benati L, et al.
Tetrahedron 53(27) , 9269-78, (1997)
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