2-(二环己基膦)-3,6-二甲氧基- 2'-4'-6'-三-I-丙基-1,1'-联苯
2-(二环己基膦)-3,6-二甲氧基- 2'-4'-6'-三-I-丙基-1,1'-联苯结构式
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常用名 | 2-(二环己基膦)-3,6-二甲氧基- 2'-4'-6'-三-I-丙基-1,1'-联苯 | 英文名 | BrettPhos |
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| CAS号 | 1070663-78-3 | 分子量 | 536.768 | |
| 密度 | N/A | 沸点 | 607.7±55.0 °C at 760 mmHg | |
| 分子式 | C35H53O2P | 熔点 | 191-193℃ | |
| MSDS | 中文版 美版 | 闪点 | 404.5±31.8 °C |
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Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions employing dialkylbiaryl phosphine ligands.
Acc. Chem. Res. 41 , 1461, (2008) The cores of many types of polymers, ligands, natural products, and pharmaceuticals contain biaryl or substituted aromatic structures, and efficient methods of synthesizing these structures are crucial to the work of a broad spectrum of organic chemists. Rece... |
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Biaryl phosphane ligands in palladium-catalyzed amination.
Angew. Chem. Int. Ed. Engl. 47 , 6338, (2008) Palladium-catalyzed amination reactions of aryl halides have undergone rapid development in the last 12 years, largely driven by the implementation of new classes of ligands. Biaryl phosphanes have proven to provide especially active catalysts in this context... |
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Dialkylbiaryl Phosphines in Pd-Catalyzed Amination: A User's Guide.
Chem. Sci. 2 , 27, (2011) Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions and have been applied in a range of contexts. This review attempts to aid the reader in the selection of the best choice of reaction conditions and ligand of this cla... |
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BrettPhos ligand supported palladium-catalyzed C-O bond formation through an electronic pathway of reductive elimination: fluoroalkoxylation of activated aryl halides.
Chemistry 20(44) , 14218-25, (2014) We report an unprecedented BrettPhos ligand supported Pd-catalyzed CO bond-forming reaction of activated aryl halides with primary fluoroalkyl alcohols. We demonstrate that the Phosphine ligand (BrettPhos) possesses the property of altering the mechanistic p... |