1,2-苯二硫醇
1,2-苯二硫醇结构式
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常用名 | 1,2-苯二硫醇 | 英文名 | benzenedithiol |
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| CAS号 | 17534-15-5 | 分子量 | 142.242 | |
| 密度 | 1.2±0.1 g/cm3 | 沸点 | 239.3±13.0 °C at 760 mmHg | |
| 分子式 | C6H6S2 | 熔点 | 22-24 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 103.9±0.0 °C |
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Investigation of chemically modified barium titanate beads as surface-enhanced Raman scattering (SERS) active substrates for the detection of benzene thiol, 1,2-benzene dithiol, and rhodamine 6G.
Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 79(3) , 456-61, (2011) SERS active surfaces were prepared by depositing silver films using Tollen's reaction on to barium titanate beads. The SERS activity of the resulting surfaces was probed using two thiols (benzene thiol and 1,2-benzene dithiol) and rhodamine 6G. The intensity ... |
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Vibrational markers for the open-shell character of transition metal bis-dithiolenes: an infrared, resonance raman, and quantum chemical study.
J. Am. Chem. Soc. 128(13) , 4422-36, (2006) Transition metal complexes involving the benzene-1,2-dithiol (L(2-)) and Sellmann's 3,5-di-tert-butylbenzene-1,2-dithiol(L(Bu 2-)) ligands have been studied by UV-vis, infrared (IR), and resonance Raman (rR) spectroscopies. Raman spectra were obtained in reso... |
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In vivo and in vitro evaluation of highly specific thiolate carrier group copper(II) and zinc(II) complexes on Ehrlich ascites carcinoma tumor model.
Eur. J. Med. Chem. 45(11) , 5438-51, (2010) A new series of copper(II) and zinc(II) complexes have been designed and synthesized using a new type of Schiff bases derived from the reaction of 3-(3-phenyl-allylidene)-pentane-2,4-dione with para substituted aniline and benzene-1,2-dithiol. Their structure... |
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Lee M, et al.
RSC Advances 5 , 86402-86406, (2015)
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Zinc, cadmium, and mercury 1,2-benzenedithiolates with intramolecular NH...S hydrogen bonds.
Inorg. Chem. 47(7) , 2837-48, (2008) Mononuclear Zn, Cd, and Hg 1,2-benzenedithiolates with intramolecular NH...S hydrogen bonds, [M(II){1,2-S2-3,6-(RCONH)2C6H2}2](2-) (R = CH 3, t-Bu; M = Zn, Cd, Hg), were synthesized and characterized by X-ray analysis and spectral measurements. The presence o... |
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Description of the ground-state covalencies of the bis(dithiolato) transition-metal complexes from X-ray absorption spectroscopy and time-dependent density-functional calculations.
Chemistry 13(10) , 2783-97, (2007) The electronic structures of [M(L(Bu))(2)](-) (L(Bu)=3,5-di-tert-butyl-1,2-benzenedithiol; M=Ni, Pd, Pt, Cu, Co, Au) complexes and their electrochemically generated oxidized and reduced forms have been investigated by using sulfur K-edge as well as metal K- a... |
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Quantitative determination of dithiocarbamates in human plasma, serum, erythrocytes and urine: pharmacokinetics of broccoli sprout isothiocyanates in humans.
Clin. Chim. Acta 316(1-2) , 43-53, (2002) Humans are exposed to substantial quantities of isothiocyanates and glucosinolates from vegetables. Since dietary isothiocyanates are widely regarded as potentially important chemoprotectors against cancer, reliable methods for measuring the plasma and tissue... |
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Quantitative determination of isothiocyanates, dithiocarbamates, carbon disulfide, and related thiocarbonyl compounds by cyclocondensation with 1,2-benzenedithiol.
Anal. Biochem. 239(2) , 160-7, (1996) A recently developed UV spectroscopic method for quantitating isothiocyanates (R-N=C=S) at the nanomole level is based on the observation that the highly electrophilic central carbon atom of the -N=C=S group can undergo successive nucleophilic additions with ... |
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The 1,2-benzenedithiole-based cyclocondensation assay: a valuable tool for the measurement of chemopreventive isothiocyanates.
Crit. Rev. Food Sci. Nutr 52(6) , 525-32, (2012) Many naturally occurring isothiocyanates (ITCs) show highly promising chemopreventive activities. Humans are commonly exposed to these compounds through the consumption of cruciferous vegetables which are the main source of dietary ITCs. Dietary ITCs may play... |
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A dinuclear, triple-stranded helicate with a diamide-bridged catechol/benzenedithiol ligand.
Angew. Chem. Int. Ed. Engl. 43(36) , 4807-10, (2004)
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