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1-二苯基膦-1''-(二叔丁基膦基)二茂铁

1-二苯基膦-1''-(二叔丁基膦基)二茂铁结构式
1-二苯基膦-1''-(二叔丁基膦基)二茂铁结构式
品牌特惠专场
常用名 1-二苯基膦-1''-(二叔丁基膦基)二茂铁 英文名 1-diphenylphosphino-1'-(di-tert-butylph&
CAS号 95408-38-1 分子量 514.39900
密度 N/A 沸点 N/A
分子式 C30H36FeP2 熔点 75-79ºC(lit.)
MSDS 美版 闪点 N/A

Endo-selective Pd-catalyzed silyl methyl Heck reaction.

J. Am. Chem. Soc. 136(52) , 17926-9, (2014)

A palladium (Pd)-catalyzed endo-selective Heck reaction of iodomethylsilyl ethers of phenols and aliphatic alkenols has been developed. Mechanistic studies reveal that this silyl methyl Heck reaction operates via a hybrid Pd-radical process and that the silic...