2,2′-[(1R,3R)-2,3,5,10-四氢-5,10-二氧-2-苯基-1H-[1,2,4]二氮杂磷杂环戊烷[1,2-b]酞嗪-1,3-二基]双[N-[(1S)-1-苯乙基]苯甲酰胺]
![2,2′-[(1R,3R)-2,3,5,10-四氢-5,10-二氧-2-苯基-1H-[1,2,4]二氮杂磷杂环戊烷[1,2-b]酞嗪-1,3-二基]双[N-[(1S)-1-苯乙基]苯甲酰胺]结构式](https://image.chemsrc.com/caspic/083/615257-74-4.png)
2,2′-[(1R,3R)-2,3,5,10-四氢-5,10-二氧-2-苯基-1H-[1,2,4]二氮杂磷杂环戊烷[1,2-b]酞嗪-1,3-二基]双[N-[(1S)-1-苯乙基]苯甲酰胺]结构式
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常用名 | 2,2′-[(1R,3R)-2,3,5,10-四氢-5,10-二氧-2-苯基-1H-[1,2,4]二氮杂磷杂环戊烷[1,2-b]酞嗪-1,3-二基]双[N-[(1S)-1-苯乙基]苯甲酰胺] | 英文名 | 2,2μ-[(1R,3R)-2,3,5,10-Tetrahydro-5,10-dioxo-2-phenyl-1H-[1,2,4]diazaphospholo[1,2-b]phthalazine-1,3-diyl]bis[N-[(1S)-1-phenylethyl]benzamide] |
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| CAS号 | 615257-74-4 | 分子量 | 742.80000 | |
| 密度 | N/A | 沸点 | N/A | |
| 分子式 | C46H39N4O4P | 熔点 | 258-262 °C | |
| MSDS | 美版 | 闪点 | N/A |
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Highly active, regioselective, and enantioselective hydroformylation with Rh catalysts ligated by Bis-3,4-diazaphospholanes.
J. Am. Chem. Soc. 127 , 5040, (2005) Azines made by the reaction of hydrazine with ortho-formylbenzoic acid react with 1,2-diphosphinobenzene and either succinyl chloride or phthaloyl chloride in ca. 30% yield to give rac-bis-3,4-diazaphospholanes bearing benzoic acid groups in the 2 and 5 posit... |
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Highly regio- and enantioselective asymmetric hydroformylation of olefins mediated by 2,5-disubstituted phospholane ligands.
Angew. Chem. Int. Ed. Engl. 44 , 5834, (2005)
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