间氯苯丙酮
间氯苯丙酮结构式
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常用名 | 间氯苯丙酮 | 英文名 | 3'-Chloropropiophenone |
|---|---|---|---|---|
| CAS号 | 34841-35-5 | 分子量 | 168.62 | |
| 密度 | 1.1±0.1 g/cm3 | 沸点 | 246.8±0.0 °C at 760 mmHg | |
| 分子式 | C9H9ClO | 熔点 | 45-47 °C(lit.) | |
| MSDS | 美版 | 闪点 | 122.7±13.7 °C |
|
Highly enantioselective catalytic phenylation of ketones with a constrained geometry titanium catalyst.
Org. Lett. 5(20) , 3641-4, (2003) [reaction: see text] The catalytic asymmetric addition of phenyl groups from diphenylzinc to ketones is reported. The catalyst, generated from a dihydroxy bis(sulfonamide) ligand and titanium tetraisopropoxide, gives good to excellent enantioselectivities wit... |
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