反次亚硝酸钠水合物
反次亚硝酸钠水合物结构式
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常用名 | 反次亚硝酸钠水合物 | 英文名 | SODIUM TRANS-HYPONITRITE HYDRATE |
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| CAS号 | 60884-94-8 | 分子量 | 124.00700 | |
| 密度 | N/A | 沸点 | N/A | |
| 分子式 | H2N2Na2O3 | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | N/A |
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The use of cyclic nitroxide radicals as HNO scavengers.
J. Inorg. Biochem. 118 , 155-61, (2013) Reduction of cyclic stable nitroxides (RNO) by HNO to the respective hydroxylamines (RNO-H) has been demonstrated using EPR spectrometry. HNO shows low reactivity toward piperidine, pyrrolidine and nitronyl nitroxides with rate constants below 1.4 × 10(5)M(-1... |
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Linkage isomerization in heme-NOx compounds: understanding NO, nitrite, and hyponitrite interactions with iron porphyrins.
Inorg. Chem. 49(14) , 6253-66, (2010) Nitric oxide (NO) and its derivatives such as nitrite and hyponitrite are biologically important species of relevance to human health. Much of their physiological relevance stems from their interactions with the iron centers in heme proteins. The chemical rea... |
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The structure of the hyponitrite species in a heme Fe-Cu binuclear center.
Angew. Chem. Int. Ed. Engl. 46(13) , 2210-4, (2007)
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Hyponitrite radical, a stable adduct of nitric oxide and nitroxyl.
J. Am. Chem. Soc. 126(3) , 891-9, (2004) All major properties of the aqueous hyponitrite radicals (ONNO- and ONNOH), the adducts of nitric oxide (NO) and nitroxyl (3NO- and 1HNO), are revised. In this work, the radicals are produced by oxidation of various hyponitrite species in the 2-14 pH range wi... |
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A stable hyponitrite-bridged iron porphyrin complex.
J. Am. Chem. Soc. 131(7) , 2460-1, (2009) The coupling of two nitric oxide (NO) molecules in heme active sites is an important contributor to the conversion of NO to nitrous oxide (N(2)O) by heme-containing enzymes. Several formulations for the presumed heme-Fe{N(2)O(2)}(n-) intermediates have been p... |
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13N,15N isotope and kinetic evidence against hyponitrite as an intermediate in dentrification.
J. Biol. Chem. 255(11) , 5027-30, (1980) 13N- and 15N-labeling experiments were carried out with Paracoccus denitrificans, grown anaerobically on nitrate, to determine whether hyponitrite might be an obligatory intermediate in denitrification and a precursor of nitrous oxide. From experiments design... |
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An umpolung approach to cis-hyponitrite complexes.
Angew. Chem. Int. Ed. Engl. 41(13) , 2371-3, (2002)
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Structural and mechanistic analysis through electronic spectra: aqueous hyponitrite radical (N2O2-) and nitrosyl hyponitrite anion (N3O3-).
J. Phys. Chem. A 115(43) , 12004-10, (2011) Aqueous hyponitrite radical (N(2)O(2)(-)) and nitrosyl hyponitrite anion (N(3)O(3)(-)) are important intermediates in the reductive chemistry of NO. The structures and absorption spectra of various hydrated isomers of these compounds were investigated in this... |
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An experimental and theoretical evaluation of the reactions of silver hyponitrite with phosphorus halides. In search of the elusive phosphorus-containing hyponitrites.
J. Phys. Chem. A 109(7) , 1420-9, (2005) In the reaction of F2PBr, F2P(O)Br, (C6F5)2PBr, (CH3)2P(S)Br, and (CH3)2P(O)Cl with silver hyponitrite (AgON=NOAg), nitrous oxide (N2O) and mu-oxo phosphorus species were obtained in all cases rather than the plausible hyponitrite alternative. Theoretical cal... |
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Banks, J.T. et al.
J. Am. Chem. Soc. 115 , 2473, (1993)
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