五乙酸α-D-甘露糖
五乙酸α-D-甘露糖结构式
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常用名 | 五乙酸α-D-甘露糖 | 英文名 | alpha-D-Mannose pentaacetate |
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| CAS号 | 4163-65-9 | 分子量 | 390.33900 | |
| 密度 | 1.3g/cm3 | 沸点 | 434.8ºC at 760mmHg | |
| 分子式 | C16H22O11 | 熔点 | 64-75ºC | |
| MSDS | 中文版 美版 | 闪点 | 188.1ºC |
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Novel synthetic inhibitors of selectin-mediated cell adhesion: synthesis of 1,6-bis[3-(3-carboxymethylphenyl)-4-(2-alpha-D- mannopyranosyloxy)phenyl]hexane (TBC1269).
J. Med. Chem. 41 , 1099-1111, (1998) Reports of a high-affinity ligand for E-selectin, sialyl di-Lewis(x) (sLe(x)Le(x), 1), motivated us to incorporate modifications to previously reported biphenyl-based inhibitors that would provide additional interactions with the protein. These compounds were... |
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Stereospecific entry to [4.5]spiroketal glycosides using alkylidenecarbene C-H insertion.
Org. Lett. 4 , 489-92, (2002) [reaction: see text] A novel method for the stereospecific preparation of [4.5]spiroketal glycosides utilizing the 1,5 C-H bond insertion of alkylidenecarbenes is described. Treatment of 2-oxopropyl beta-pyranosides A with lithium (trimethylsilyl)diazomethane... |
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