2-萘乙醇
2-萘乙醇结构式
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常用名 | 2-萘乙醇 | 英文名 | naphthalen-1-ethanol |
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| CAS号 | 1485-07-0 | 分子量 | 172.223 | |
| 密度 | 1.1±0.1 g/cm3 | 沸点 | 309.8±0.0 °C at 760 mmHg | |
| 分子式 | C12H12O | 熔点 | 66-68ºC | |
| MSDS | 中文版 美版 | 闪点 | 150.6±15.1 °C |
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The role of weak hydrogen bonds in chiral recognition.
Phys. Chem. Chem. Phys. 13(40) , 17916-29, (2011) Chiral recognition has been studied in neutral or ionic weakly bound complexes isolated in the gas phase by combining laser spectroscopy and quantum chemical calculations. Neutral complexes of the two enantiomers of lactic ester derivatives with chiral chromo... |
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Fluorescence detection of surface-bound intermediates produced from UV photoreactivity of alkylsiloxane SAMs.
J. Am. Chem. Soc. 126(8) , 2260-1, (2004) Detection and quantification of submonolayer coverage surface species is not trivial. We have developed a novel method sensitive to surface-bound chemical functional groups as low as 10(11) molecules/cm(2) by specific covalent attachment of fluorescent chromo... |
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Chiral recognition between lactic acid derivatives and an aromatic alcohol in a supersonic expansion: electronic and vibrational spectroscopy.
Phys. Chem. Chem. Phys. 8(8) , 1007-16, (2006) Jet-cooled diastereoisomeric complexes formed between a chiral probe, (+/-)-2-naphthyl-1-ethanol, and chiral lactic acid derivatives have been characterised by laser-induced fluorescence and IR fluorescence-dip spectroscopy. Complexes with non chiral alpha-hy... |
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Resolution of 1-(2-naphthyl)ethanol by a combination of an enzyme-catalyzed kinetic resolution with a fluorous triphasic separative reaction.
Org. Lett. 4(15) , 2585-7, (2002) [reaction: see text] Kinetic resolution of a fluorous ester rac-1 with Candida antarctica B lipase provided a mixture of enantioenriched alcohol (R)-2 and fluorous ester (S)-1. The mixture was subjected to a fluorous triphasic reaction to give both enantiomer... |
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Enantiomer separation by complexation SFC on immobilized Chirasil-nickel and Chirasil-zinc.
J. Biochem. Biophys. Methods 43(1-3) , 223-40, (2000) The use of complexation SFC for enantiomer separation of Lewis base selectands on chiral nickel(II)- and zinc(II)-bis[(3-heptafluorobutanoyl)-10-methylene-(1R)-camphora te] chemically bonded to poly(dimethylsiloxane) (Chirasil-nickel and Chirasil-zinc) and em... |
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Resolution and synthesis of (S)-1-(2-naphthyl)ethanol with immobilized pea protein: as a new biocatalyst.
Biosci. Biotechnol. Biochem. 63(11) , 1991-2, (1999) (S)-1-(2-Naphthyl)ethanol was yielded by immobilized pea (Pisum sativum L.) protein (IPP) from (R, S) 2-naphthyl ethanol (> 99% ee, yield; about 50%), in which the (R)-enantiomer was selectively oxidized to 2-acetonaphthone. IPP could be reused consecutively ... |
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Resolution and synthesis of optically active alcohols with immobilized water-soluble proteins from green pea, soybean and buckwheat as new bio-catalysts.
Biosci. Biotechnol. Biochem. 64(4) , 781-4, (2000) Kinetic resolution of racemic alcohols, (+/-)-1-(4-substituted phenyl)ethanol and (+/-)-1-(2-naphthyl)ethanol, was done with immobilized green pea, soybean, or buckwheat proteins. The resolution was done stereoselectively by oxidizing only one enantiomer of a... |
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Chemoenzymatic synthesis of optically active, biodegradable polymers based on phenyl- and naphthyl-ethanols esterified with divinyladipate.
Biotechnol. Lett. 26(8) , 665-70, (2004) For the purpose of developing a new synthetic polymer containing an asymmetric molecule branch, three racemic alcohols, i.e. 1-phenylethanol, 1-(4-methylphenyl)ethanol and 1-(2-naphthyl)ethanol, were esterified enzymatically with divinyladipate using a lipase... |
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Alkoxyacetyl (AAc) group as a useful linker for organic synthesis on poly (ethylene glycol) support. Oikawa M, et al.
Tetrahedron Lett. 45(11) , 2371-75, (2004)
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