N-乙酰-L-缬氨酸
N-乙酰-L-缬氨酸结构式
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常用名 | N-乙酰-L-缬氨酸 | 英文名 | Acetylvaline |
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| CAS号 | 96-81-1 | 分子量 | 159.183 | |
| 密度 | 1.1±0.1 g/cm3 | 沸点 | 362.2±25.0 °C at 760 mmHg | |
| 分子式 | C7H13NO3 | 熔点 | 165 °C | |
| MSDS | 美版 | 闪点 | 172.8±23.2 °C |
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N-Acyl Amino Acid Ligands for Ruthenium(II)-Catalyzed meta-C-H tert-Alkylation with Removable Auxiliaries.
J. Am. Chem. Soc. 137(43) , 13894-901, (2015) Acylated amino acid ligands enabled ruthenium(II)-catalyzed C-H functionalizations with excellent levels of meta-selectivity. The outstanding catalytic activity of the ruthenium(II) complexes derived from monoprotected amino acids (MPAA) set the stage for the... |
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Ligand-accelerated C-H activation reactions: evidence for a switch of mechanism.
J. Am. Chem. Soc. 132(40) , 14137-51, (2010) Initial rate studies have revealed dramatic acceleration in aerobic Pd(II)-catalyzed C-H olefination reactions of phenylacetic acids when mono-N-protected amino acids are used as ligands. In light of these findings, systematic ligand tuning was undertaken, wh... |
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