(1S,2S,3R,5S)-(+)-2,3-蒎烷二醇
(1S,2S,3R,5S)-(+)-2,3-蒎烷二醇结构式
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常用名 | (1S,2S,3R,5S)-(+)-2,3-蒎烷二醇 | 英文名 | (1S,2S,3R,5S)-(+)-2,3-Pinanediol |
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| CAS号 | 18680-27-8 | 分子量 | 170.25 | |
| 密度 | 1.1±0.1 g/cm3 | 沸点 | 263.7±8.0 °C at 760 mmHg | |
| 分子式 | C10H18O2 | 熔点 | 53-57ºC | |
| MSDS | 中文版 美版 | 闪点 | 120.8±13.0 °C |
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Enantio- and diastereoselective synthesis of syn-beta-hydroxyallylsilanes via a chiral (Z)-gamma-silylallylboronate.
Org. Lett. 9 , 4315, (2007) syn-beta-Hydroxyallylsilanes of general structure 11 and 28 are prepared in 50-86% yield and 91-95% ee (for aliphatic aldehydes; 50% ee for benzaldehyde) via the BF(3).Et(2)O-promoted gamma-silylallylboration reactions, using reagents 14 and 15. |
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J. Org. Chem. 58 , 3600, (1993)
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Tetrahedron 49 , 1009, (1993)
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