四氢噻喃-4-酮
四氢噻喃-4-酮结构式
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常用名 | 四氢噻喃-4-酮 | 英文名 | Tetrahydrothiopyran-4-one |
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| CAS号 | 1072-72-6 | 分子量 | 116.18 | |
| 密度 | 1.1±0.1 g/cm3 | 沸点 | 218.7±33.0 °C at 760 mmHg | |
| 分子式 | C5H8OS | 熔点 | 60-64 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 105.5±11.1 °C |
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Synthesis , 672, (1994)
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J. Heterocycl. Chem. 31 , 397, (1994)
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J. Heterocycl. Chem. 30 , 81, (1993)
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Synlett , 1605, (2007)
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Influence of the beta-alkoxy group on the diastereoselectivity of Aldol reactions of tetrahydro-4H-thiopyran-4-one with 4-Alkoxytetrahydro-2H-thiopyran-3-carboxaldehydes.
J. Org. Chem. 67(5) , 1618-29, (2002) The diastereoselectivity of the aldol reaction of tetrahydro-4H-thiopyran-4-one (3) with 1,4-dioxa-8-thiaspiro[4.5]decane-6-carboxaldehyde (9a) under a variety of conditions is examined. Under optimized conditions, three of the four possible diastereomers fro... |
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Asymmetric synthesis of hexapropionate synthons by sequential enantiotopic group selective enolization of meso diketones.
Org. Lett. 8(12) , 2631-4, (2006) Meso 1,9-diketones (six to seven stereocenters) are readily obtained by stepwise or simultaneous two-directional aldol reactions of tetrahydro-4H-thiopyran-4-one with a thiopyran-derived aldehyde or dialdehyde. Enantioselective enolizations of these diketones... |
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J.H. van Boom et al.
J. Chem. Soc. Chem. Commun. , 766, (1972)
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