(R)-C3-TunePhos-钌络合物
(R)-C3-TunePhos-钌络合物结构式
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常用名 | (R)-C3-TunePhos-钌络合物 | 英文名 | [Chloro(R)-C3-TunePhos)(p-cymene)ruthenium(II)] chloride |
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| CAS号 | 905709-79-7 | 分子量 | 900.81200 | |
| 密度 | N/A | 沸点 | N/A | |
| 分子式 | C49H46Cl2O2P2Ru | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | N/A |
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Synthesis of chiral bisphosphines with tunable bite angles and their applications in asymmetric hydrogenation of beta-ketoesters.
J. Org. Chem. 65 , 6223, (2000)
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Enantioselective hydrogenation of tetrasubstituted olefins of cyclic beta-(acylamino)acrylates.
J. Am. Chem. Soc. 125 , 9570, (2003) Hydrogenation of a series of cyclic beta-(acylamino)acrylates with tetrasubstituted olefins has been accomplished successfully with the use of Ru catalysts with chiral biaryl ligands such as C3-TunaPhos, and up to over 99% ee's have been achieved. This method... |
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Highly enantioselective asymmetric hydrogenation of alpha-phthalimide ketone: an efficient entry to enantiomerically pure amino alcohols.
J. Am. Chem. Soc. 126 , 1626, (2004) A new type of alpha-phthalimide ketones was hydrogenated in excellent enantioselectivity by using a Ru-(C3-TunePhos) complex as the catalyst. Up to 10 000 turnovers have been achieved in more than 99% ee in the hydrogenation reaction. A dynamic kinetic resolu... |