![]() 氯(2-二环己基膦基-2 ,4 ,6 -三异丙基-1,1 -联苯基)[2-(2 -氨基-1,1 -联苯)]钯(II)结构式
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常用名 | 氯(2-二环己基膦基-2 ,4 ,6 -三异丙基-1,1 -联苯基)[2-(2 -氨基-1,1 -联苯)]钯(II) | 英文名 | chloro(2-dicyclohexylphosphino-2',4',6'-triisoporpyl-1,1'-biphenyl)[2-(2'-amino-1,1'-biphenyl)] palladium (II) |
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CAS号 | 1310584-14-5 | 分子量 | 784.78800 | |
密度 | N/A | 沸点 | N/A | |
分子式 | C45H57ClNPPd | 熔点 | 202-210 °C | |
MSDS | 中文版 美版 | 闪点 | N/A |
Palladium-catalyzed α-arylation of 2-chloroacetates and 2-chloroacetamides.
J. Org. Chem. 78(8) , 4123-31, (2013) A method has been developed for the Pd-catalyzed synthesis of α-(hetero)aryl esters and amides through a Suzuki-Miyaura cross-coupling reaction. This method avoids the use of strong base, does not necessitate inert or low temperature formation of reagents, an... |
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Pd-catalyzed Suzuki-Miyaura cross-coupling reactions between sulfamates and potassium Boc-protected aminomethyltrifluoroborates.
Org. Lett. 15(10) , 2534-7, (2013) Sulfamates were studied as the electrophilic partners in the palladium-catalyzed Suzuki-Miyaura cross-coupling reaction with potassium Boc-protected primary and secondary aminomethyltrifluoroborates. A broad range of substrates was successfully coupled to pro... |
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Potassium Boc-protected secondary aminomethyltrifluoroborates: synthesis and Suzuki-Miyaura cross-coupling reactions.
Org. Lett. 14(17) , 4458-61, (2012) Seven potassium Boc-protected secondary aminomethyltrifluoroborates were prepared in a standardized two-step process. The Suzuki-Miyaura cross-coupling reaction was studied with this new class of nucleophiles, and a large variety of aryl and hetaryl chlorides... |
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