Mattson Boronate Urea Pinacol Ester
Mattson Boronate Urea Pinacol Ester结构式
|
常用名 | Mattson Boronate Urea Pinacol Ester | 英文名 | Mattson Boronate Urea Pinacol Ester |
|---|---|---|---|---|
| CAS号 | 1538637-10-3 | 分子量 | 474.20 | |
| 密度 | N/A | 沸点 | N/A | |
| 分子式 | C21H21BF6N2O3 | 熔点 | 230.39°C | |
| MSDS | 美版 | 闪点 | N/A |
|
Urea-catalyzed N-H insertion-arylation reactions of nitrodiazoesters.
J. Org. Chem. 79(11) , 4832-42, (2014) The power of hydrogen-bond donor catalysis has been harnessed to elicit and control carbene-like reactivity from nitrodiazoesters. Specifically, select ureas have been identified as effective catalysts for N-H insertion and multicomponent coupling reactions o... |
|
|
Arylation of diazoesters by a transient N-H insertion organocascade.
Angew. Chem. Int. Ed. Engl. 52(43) , 11317-20, (2013) It takes two: A unique organocatalyzed cascade for the unsymmetric double arylation of α-nitrodiazoesters is described. This organocascade features the strategic use of carbene-activating anilines in conjunction with a urea catalyst, thus allowing for the syn... |
|
|
Urea-catalyzed construction of oxazinanes.
Org. Biomol. Chem. 11(35) , 5793-7, (2013) Highly functionalized oxazinanes are efficiently prepared through urea-catalyzed formal [3 + 3] cycloaddition reactions of nitrones and nitrocyclopropane carboxylates. The reaction system is general with respect to both the nitrocyclopropane carboxylates and ... |
|
|
Internal Lewis acid assisted ureas: tunable hydrogen bond donor catalysts.
Chem. Commun. (Camb.) 49 , 4289-4291, (2013) The strategic incorporation of internal Lewis acids onto urea scaffolds gives rise to a family of tunable hydrogen bond donor catalysts. The nature of the Lewis acid and associated ligands affects the urea polarization, acidity, and activity in reactions of n... |
|
|
Boronate urea activation of nitrocyclopropane carboxylates.
Org. Lett. 14(2) , 444-7, (2012) Boronate ureas operate as catalysts for the activation of nitrocyclopropane carboxylates in nucleophilic ring-opening reactions. A variety of amines were found to open the urea-activated nitrocyclopropane carboxylates, generating highly useful nitro ester bui... |
|
|
Internal Lewis acid assisted hydrogen bond donor catalysis.
Org. Lett. 13(4) , 716-9, (2011) Boronate ureas are introduced as a new class of noncovalent catalysts for conjugate addition reactions with enhanced activity. Through intramolecular coordination of the urea functionality to a strategically placed Lewis acid, rate enhancements up to 10 times... |