双(三叔丁基膦)钯(0)
双(三叔丁基膦)钯(0)结构式
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常用名 | 双(三叔丁基膦)钯(0) | 英文名 | Bis(tri-t-butylphosphine)palladium |
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| CAS号 | 53199-31-8 | 分子量 | 511.05 | |
| 密度 | N/A | 沸点 | 229.4ºC at 760mmHg | |
| 分子式 | C24H54P2Pd | 熔点 | >300 °C | |
| MSDS | 中文版 美版 | 闪点 | 94.6ºC |
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Pd/P(t-Bu)(3): a mild and general catalyst for Stille reactions of aryl chlorides and aryl bromides.
J. Am. Chem. Soc. 124 , 6343, (2003) Pd/P(t-Bu)(3) serves as an unusually reactive catalyst for Stille reactions of aryl chlorides and bromides, providing solutions to a number of long-standing challenges. An unprecedented array of aryl chlorides can be cross-coupled with a range of organotin re... |
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Sequential assembly strategy for tetrasubstituted olefin synthesis using vinyl 2-pyrimidyl sulfide as a platform.
J. Am. Chem. Soc. 126 , 11778, (2004) We have developed a programmable and diversity-oriented synthetic scheme for tetrasubstituted olefins through a site-selective and sequential assembly of pi-components onto a C=C core of vinyl 2-pyrimidyl sulfide. Noteworthy features are that (i) all componen... |
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Aqueous hydroxide as a base for palladium-catalyzed amination of aryl chlorides and bromides.
J. Org. Chem. 67 , 6479, (2002) The amination of aryl halides in the presence of inexpensive and air-stable alkali metal hydroxide bases and Pd[P(t-Bu)3]2 as catalyst gave arylamines in high yields. The reactions were conducted with a catalytic amount of cetyltrimethylammonium bromide as ph... |
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Chemoselective and regiospecific Suzuki coupling on a multisubstituted sp(3)-carbon in 1,1-diborylalkanes at room temperature.
J. Am. Chem. Soc. 132 , 11033, (2010) The palladium-catalyzed Suzuki-Miyaura cross-coupling on a multisubstituted sp(3)-carbon in 1,1-diborylalkanes was achieved at room temperature. The generation of a monoborate intermediate by virtue of the adjacent B atom could result in the chemoselective co... |
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Direct carbamoylation of alkenyl halides.
Org. Lett. 5 , 4947, (2003) Alkenyl chlorides and bromides are converted into tertiary enamides by treatment with a carbamoylsilane in toluene at 110 degrees C in the presence of phosphine-palladium(0) catalysts. [reaction: see text] |
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Negishi, E.-I.; Shi, J.-C.; Zeng, X.
Tetrahedron 61 , 9886, (2005)
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