反式-2-苯基环丙烷-羧酸结构式
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常用名 | 反式-2-苯基环丙烷-羧酸 | 英文名 | 2-Phenylcyclopropanecarboxylic acid |
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| CAS号 | 939-90-2 | 分子量 | 162.185 | |
| 密度 | 1.3±0.1 g/cm3 | 沸点 | 317.1±31.0 °C at 760 mmHg | |
| 分子式 | C10H10O2 | 熔点 | 86-88 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 144.3±19.5 °C |
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Efficient syntheses of four stable-isotope labeled (1R)-menthyl (1S,2S)-(+)-2-phenylcyclopropanecarboxylates.
Org. Biomol. Chem. 4(14) , 2777-84, (2006) Many carbenoid cyclopropanation reactions promoted by chiral catalysts give product mixtures reflecting impressive diastereo- and enantioselectivities. Few provide a single chiral product efficiently. This limitation has been overcome in cyclopropanations of ... |
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Hydrogen bonding and ring asymmetry in a substituted cyclopropane: (+)-trans-(1S,2S)-2-phenylcyclopropanecarboxylic acid at 208 K.
Acta Crystallogr. C 53 ( Pt 9) , 1280-2, (1997) The title compound, C10H10O2, crystallized in space group P2(1) with two molecules in the asymmetric unit. In this structure, hydrogen bonding of the cyclic dimer type [with O ... O 2.623(2)-2.637(2)A] links the two molecules of the asymmetric unit. The two c... |
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Hydrogen bonding and ring asymmetry in (+/-)-cis-2-phenylcyclopropanecarboxylic acid.
Acta Crystallogr. C 53 ( Pt 12) , 1989-91, (1997) The title compound, (+/-)-cis-2-phenylcyclopropanecarboxylic acid, C10H10O2, crystallized in the centrosymmetric space group P2(1)/n. The hydrogen bonding is of the cyclic dimer type about a center of symmetry; the Odonor...Oacceptor distance is 2.645 (2) A. ... |
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