(S)-1,13-二(二苯基膦基)-7,8-二氢-6H-二苯并[f,h][1,5]二氧杂环壬烷
![(S)-1,13-二(二苯基膦基)-7,8-二氢-6H-二苯并[f,h][1,5]二氧杂环壬烷结构式](https://image.chemsrc.com/caspic/325/486429-99-6.png)
(S)-1,13-二(二苯基膦基)-7,8-二氢-6H-二苯并[f,h][1,5]二氧杂环壬烷结构式
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常用名 | (S)-1,13-二(二苯基膦基)-7,8-二氢-6H-二苯并[f,h][1,5]二氧杂环壬烷 | 英文名 | (S)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine |
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| CAS号 | 486429-99-6 | 分子量 | 594.61800 | |
| 密度 | N/A | 沸点 | 709.9±60.0 ℃(Predicted) | |
| 分子式 | C39H32O2P2 | 熔点 | 153-161ºC(lit.) | |
| MSDS | 中文版 美版 | 闪点 | N/A |
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Synthesis of chiral bisphosphines with tunable bite angles and their applications in asymmetric hydrogenation of beta-ketoesters.
J. Org. Chem. 65 , 6223, (2000)
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Enantioselective hydrogenation of tetrasubstituted olefins of cyclic beta-(acylamino)acrylates.
J. Am. Chem. Soc. 125 , 9570, (2003) Hydrogenation of a series of cyclic beta-(acylamino)acrylates with tetrasubstituted olefins has been accomplished successfully with the use of Ru catalysts with chiral biaryl ligands such as C3-TunaPhos, and up to over 99% ee's have been achieved. This method... |
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Highly enantioselective asymmetric hydrogenation of alpha-phthalimide ketone: an efficient entry to enantiomerically pure amino alcohols.
J. Am. Chem. Soc. 126 , 1626, (2004) A new type of alpha-phthalimide ketones was hydrogenated in excellent enantioselectivity by using a Ru-(C3-TunePhos) complex as the catalyst. Up to 10 000 turnovers have been achieved in more than 99% ee in the hydrogenation reaction. A dynamic kinetic resolu... |