二氯[9,9-二甲基-4,5-双(二苯基膦)氧杂蒽]钯(II)
![二氯[9,9-二甲基-4,5-双(二苯基膦)氧杂蒽]钯(II)结构式](https://image.chemsrc.com/caspic/255/205319-10-4.png)
二氯[9,9-二甲基-4,5-双(二苯基膦)氧杂蒽]钯(II)结构式
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常用名 | 二氯[9,9-二甲基-4,5-双(二苯基膦)氧杂蒽]钯(II) | 英文名 | Dichloro[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene]palladium(II) |
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| CAS号 | 205319-10-4 | 分子量 | 755.94 | |
| 密度 | N/A | 沸点 | N/A | |
| 分子式 | C39H32Cl2OP2Pd | 熔点 | 287 °C(dec.) | |
| MSDS | 美版 | 闪点 | N/A |
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Palladium-catalyzed esterification of aryl halides using aryl formates without the use of external carbon monoxide.
Chem. Commun. (Camb.) 48 , 8012, (2012) Aryl formates are efficient carbon monoxide sources in palladium-catalyzed esterification of aryl halides. The carbonylation readily proceeds at ambient pressure without the use of external carbon monoxide to afford the corresponding esters in high yields. |
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Palladium-catalyzed oxidative carbonylation of benzylic C-H bonds via nondirected C(sp3)-H activation.
J. Am. Chem. Soc. 134 , 9902, (2012) A new strategy for generating benzylpalladium reactive species from toluenes via nondirected C(sp(3))-H activation has been developed. This led to construction of an efficient Pd-catalyzed reaction protocol for the oxidative carboxylation of benzylic C-H bond... |
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Improved carbonylation of heterocyclic chlorides and electronically challenging aryl bromides.
Org. Lett. 6 , 2097, (2004) [reaction: see text] Optimized conditions are described that effect the carbonylation of diverse heterocyclic chlorides to yield the desired alkyl esters. In addition, bromoanilines and bromoanisoles, which normally are poor substrates under standard carbonyl... |