trifluoromethanesulfonimide

Modify Date: 2025-08-21 10:10:21

trifluoromethanesulfonimide structure	Common Name	trifluoromethanesulfonimide
	CAS Number	82113-65-3	Molecular Weight	281.15400
	Density	1.936 g/cm3	Boiling Point	90-91 °C(lit.)
	Molecular Formula	C₂HF₆NO₄S₂	Melting Point	52-56 °C
	MSDS	Chinese USA	Flash Point	69ºC
	Symbol	GHS05	Signal Word	Danger

Name	trifluoromethanesulfonimide
Synonym	More Synonyms

Density	1.936 g/cm3
Boiling Point	90-91 °C(lit.)
Melting Point	52-56 °C
Molecular Formula	C₂HF₆NO₄S₂
Molecular Weight	281.15400
Flash Point	69ºC
Exact Mass	280.92500
PSA	97.07000
LogP	2.82770
Index of Refraction	1.523
InChIKey	ZXMGHDIOOHOAAE-UHFFFAOYSA-N
SMILES	O=S(=O)(NS(=O)(=O)C(F)(F)F)C(F)(F)F
Storage condition	2-8°C
Stability	Stable. Incompatible with strong oxidizing agents. Reacts violently with water.

trifluoromethanesulfonimide MSDS(Chinese)

Symbol	GHS05
Signal Word	Danger
Hazard Statements	H314
Supplemental HS	Reacts violently with water.
Precautionary Statements	P280-P305 + P351 + P338-P310
Personal Protective Equipment	Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
Hazard Codes	C
Risk Phrases	R34;R40
Safety Phrases	S26-S36/37/39-S45
RIDADR	UN 3265 8/PG 2
WGK Germany	3
Hazard Class	8.0
HS Code	2935009090

Lithium bis(tri...

CAS#:90076-65-6

~10%

trifluoromethan...

CAS#:82113-65-3

Literature: Agel, Friederike; Pitsch, Fee; Krull, Florian Felix; Schulz, Peter; Wessling, Matthias; Melin, Thomas; Wasserscheid, Peter Physical Chemistry Chemical Physics, 2011 , vol. 13, # 2 p. 725 - 731

Et3NH(1+)*Tf2N(1-)

CAS#:192998-66-6

~99%

trifluoromethan...

CAS#:82113-65-3

Literature: Simchen, Gerhard; Jonas, Simon Journal fuer Praktische Chemie/Chemiker-Zeitung, 1998 , vol. 340, # 6 p. 506 - 512

Sodium bis(trif...

CAS#:91742-21-1

~92%

trifluoromethan...

CAS#:82113-65-3

Literature: Desmarteau, Darryl D.; Witz, Michael Journal of Fluorine Chemistry, 1991 , vol. 52, # 1 p. 7 - 12

N-(tert-butyl)-...

CAS#:41804-81-3

trifluoromethan...

CAS#:82113-65-3

Isobutylene

CAS#:115-11-7

Literature: Gmelin Handbook: F: PerFHalOrg.SVol.3, 6.2.3.3, page 137 - 151

CF3SO2N(Na)Si(Me)3

CAS#:91742-20-0

trifluoromethan...

CAS#:82113-65-3

Literature: Chimia, , vol. 58, # 3 p. 153 - 155

Precursor 4
CAS#:90076-65-6 Lithium bis(tri... CAS#:192998-66-6 Et3NH(1+)*Tf2N(1-) CAS#:91742-21-1 Sodium bis(trif... CAS#:41804-81-3 N-(tert-butyl)-...
DownStream 7
CAS#:108388-06-3 N,1,1,1-tetrafl... CAS#:7664-39-3 HYDROFLUORIC ACID CAS#:7637-07-2 bf3 CAS#:90076-65-6 Lithium bis(tri...
CAS#:3582-05-6 trifluoromethyl... CAS#:189114-61-2 Silver(1+) bis[... CAS#:174899-82-2 1-Ethyl-3-Methy...

HS Code	2935009090
Summary	2935009090 other sulphonamides VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:35.0%

Bis (trifluoromethane) sulfonimide initiated ring-opening polymerization of octamethylcyclotetrasiloxane. Desmurs J-R, et al.

J. Organomet. Chem. 646(1) , 171-8, (2002)

Comparative Electrochemical Study of New Poly(oxyethylene)-Li Salt Complexes. Benrabah D, et al.

J. Chem. Soc., Faraday 89 , 355-359, (1993)

Synthesis of trehalose mimics by bismuth (III) triflate or bis (trifluoromethane) sulfonimide-catalyzed 1-C-methyl-D-hexopyranosylation. Yamanoi T, et al.

Tetrahedron Asymmetry 17(20) , 2914-2918, (2006)

1,1,1-trifluoro-N-(trifluoromethylsulfonyl)methanesulfonamide

MFCD00214154

Bis(trifluoromethane)sulfonimide

N,N-Bis(trifluoromethanesulfonyl)imide