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trifluoromethanesulfonimide

Names

[ CAS No. ]:
82113-65-3

[ Name ]:
trifluoromethanesulfonimide

[Synonym ]:
1,1,1-trifluoro-N-(trifluoromethylsulfonyl)methanesulfonamide
MFCD00214154
Bis(trifluoromethane)sulfonimide
N,N-Bis(trifluoromethanesulfonyl)imide

Chemical & Physical Properties

[ Density]:
1.936 g/cm3

[ Boiling Point ]:
90-91 °C(lit.)

[ Melting Point ]:
52-56 °C

[ Molecular Formula ]:
C2HF6NO4S2

[ Molecular Weight ]:
281.15400

[ Flash Point ]:
69ºC

[ Exact Mass ]:
280.92500

[ PSA ]:
97.07000

[ LogP ]:
2.82770

[ Index of Refraction ]:
1.523

[ Storage condition ]:
2-8°C

[ Stability ]:
Stable. Incompatible with strong oxidizing agents. Reacts violently with water.

MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Supplemental HS ]:
Reacts violently with water.

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C

[ Risk Phrases ]:
R34;R40

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 3265 8/PG 2

[ WGK Germany ]:
3

[ Hazard Class ]:
8.0

[ HS Code ]:
2935009090

Synthetic Route

Precursor & DownStream

Customs

[ HS Code ]: 2935009090

[ Summary ]:
2935009090 other sulphonamides VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:35.0%

Articles

Bis (trifluoromethane) sulfonimide initiated ring-opening polymerization of octamethylcyclotetrasiloxane. Desmurs J-R, et al.

J. Organomet. Chem. 646(1) , 171-8, (2002)

Comparative Electrochemical Study of New Poly(oxyethylene)-Li Salt Complexes. Benrabah D, et al.

J. Chem. Soc., Faraday 89 , 355-359, (1993)

Synthesis of trehalose mimics by bismuth (III) triflate or bis (trifluoromethane) sulfonimide-catalyzed 1-C-methyl-D-hexopyranosylation. Yamanoi T, et al.

Tetrahedron Asymmetry 17(20) , 2914-2918, (2006)


More Articles


Related Compounds

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