bf3

Modify Date: 2024-01-02 13:27:22

bf3 Structure
bf3 structure
Common Name bf3
CAS Number 7637-07-2 Molecular Weight 67.80620
Density 0.90 g/mL at 20 °C Boiling Point −100 °C(lit.)
Molecular Formula BF3 Melting Point −127 °C(lit.)
MSDS USA Flash Point 4°C
Symbol GHS02 GHS05 GHS07
GHS02, GHS05, GHS07
Signal Word Danger

 Names

Name boron trifluoride
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.90 g/mL at 20 °C
Boiling Point −100 °C(lit.)
Melting Point −127 °C(lit.)
Molecular Formula BF3
Molecular Weight 67.80620
Flash Point 4°C
Exact Mass 68.00450
LogP 0.87980
Vapour density 2.38 (21 °C, vs air)
Index of Refraction n20/D 1.38
Water Solubility MAY DECOMPOSE

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
ED2275000
CHEMICAL NAME :
Borane, trifluoro-
CAS REGISTRY NUMBER :
7637-07-2
LAST UPDATED :
199712
DATA ITEMS CITED :
38
MOLECULAR FORMULA :
B-F3
MOLECULAR WEIGHT :
67.81
WISWESSER LINE NOTATION :
FBFF

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1180 mg/m3/4H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,27,1982
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
3460 mg/m3/2H
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - cyanosis Blood - hemorrhage
REFERENCE :
FATOAO Farmakologiya i Toksikologiya (Moscow). For English translation, see PHTXA6 and RPTOAN. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.2- 1939- Volume(issue)/page/year: 35,369,1972
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
109 mg/m3/4H
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - cyanosis Blood - hemorrhage
REFERENCE :
FATOAO Farmakologiya i Toksikologiya (Moscow). For English translation, see PHTXA6 and RPTOAN. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.2- 1939- Volume(issue)/page/year: 35,369,1972 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
12800 ppb/7H/65D-I
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - fibrosis, focal (pneumoconiosis) Related to Chronic Data - death
REFERENCE :
AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 22,263,1961
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
10 mg/m3/4H/17W-I
TOXIC EFFECTS :
Sense Organs and Special Senses (Olfaction) - effect, not otherwise specified Lungs, Thorax, or Respiration - structural or functional change in trachea or bronchi Blood - changes in leukocyte (WBC) count
REFERENCE :
FATOAO Farmakologiya i Toksikologiya (Moscow). For English translation, see PHTXA6 and RPTOAN. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.2- 1939- Volume(issue)/page/year: 35(3),369,1972
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
12800 ppb/7H/65D-I
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - bronchiolar constriction Nutritional and Gross Metabolic - changes in metals, not otherwise specified Related to Chronic Data - death
REFERENCE :
AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 22,263,1961
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
3 mg/m3/4H/17W-I
REFERENCE :
FATOAO Farmakologiya i Toksikologiya (Moscow). For English translation, see PHTXA6 and RPTOAN. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.2- 1939- Volume(issue)/page/year: 35(3),369,1972 *** REVIEWS *** ACGIH TLV-CL 2.8 mg/m3 (1 ppm) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD:air-CL 1 ppm (3 mg/m3) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,26,1971 OSHA PEL (Gen Indu):CL 1 ppm (3 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):CL 1 ppm (3 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):CL 1 ppm (3 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):CL 1 ppm (3 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-ARAB Republic of Egypt:TWA 1 ppm (3 mg/m3) JAN 1993 OEL-AUSTRALIA:TWA 1 ppm (3 mg/m3) JAN 1993 OEL-AUSTRIA:TWA 1 ppm (3 mg/m3) JAN 1993 OEL-BELGIUM:STEL 1 ppm (2.8 mg/m3) JAN 1993 OEL-DENMARK:STEL 1 ppm (3 mg/m3) JAN 1993 OEL-FINLAND:TWA 1 ppm (3 mg/m3);STEL 3 ppm (8.3 mg/m3) JAN 1993 OEL-FRANCE:STEL 1 ppm (3 mg/m3) JAN 1993 OEL-GERMANY:TWA 1 ppm (3 mg/m3) JAN 1993 OEL-INDIA:TWA 1 ppm (3 mg/m3) JAN 1993 OEL-JAPAN:TWA 0.3 ppm (0.83 mg/m3) JAN 1993 OEL-THE NETHERLANDS:TWA 1 ppm (3 mg/m3) JAN 1993 OEL-THE PHILIPPINES:STEL 1 ppm (3 mg/m3) JAN 1993 OEL-RUSSIA:TWA 0.3 ppm;STEL 1 mg/m3 JAN 1993 OEL-SWITZERLAND:TWA 1 ppm (3 mg/m3);STEL 2 ppm (6 mg/m3) JAN 1993 OEL-THAILAND:TWA 1 ppm (3 mg/m3) JAN 1993 OEL-TURKEY:TWA 1 ppm (3 mg/m3) JAN 1993 OEL-UNITED KINGDOM:TWA 1 ppm (3 mg/m3);STEL 1 ppm (3 mg/m3) JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO BORON TRIFLUORIDE-air:CL 1 ppm REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 12980 No. of Facilities: 271 (estimated) No. of Industries: 10 No. of Occupations: 13 No. of Employees: 4021 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 12980 No. of Facilities: 79 (estimated) No. of Industries: 6 No. of Occupations: 10 No. of Employees: 3819 (estimated) No. of Female Employees: 524 (estimated)

 Safety Information

Symbol GHS02 GHS05 GHS07
GHS02, GHS05, GHS07
Signal Word Danger
Hazard Statements H226-H302-H314-H332-H335-H336
Supplemental HS Reacts violently with water.
Precautionary Statements P261-P280-P305 + P351 + P338-P310
Target Organs Kidney
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes F: Flammable;T+: Very toxic;
Risk Phrases R11;R14;R24/25;R26;R35;R39/23/24/25
Safety Phrases S9-S26-S28-S36/37/39-S45-S28A-S16
RIDADR UN 3286 3/PG 2
WGK Germany 3
RTECS ED2275000
Hazard Class 2.3

 Synthetic Route

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 Synonyms

fluoruredebore
Boron trifluoride
trifluoro-boran
BORON FLUORIDE
bromine trifluoride
Bortrifluorid
BF3
MFCD00011316
BoronTrifuoride
Trifluoroboron
boron trilfuoride
anca1040
EINECS 206-766-4
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