formohydrazide

Modify Date: 2024-01-02 21:54:46

formohydrazide structure	Common Name	formohydrazide
	CAS Number	624-84-0	Molecular Weight	60.055
	Density	1.1±0.1 g/cm3	Boiling Point	129.7±23.0 °C at 760 mmHg
	Molecular Formula	CH₄N₂O	Melting Point	52-57 °C(lit.)
	MSDS	USA	Flash Point	32.2±22.6 °C
	Symbol	GHS07	Signal Word	Warning

Name	Formylhydrazine
Synonym	More Synonyms

Density	1.1±0.1 g/cm3
Boiling Point	129.7±23.0 °C at 760 mmHg
Melting Point	52-57 °C(lit.)
Molecular Formula	CH₄N₂O
Molecular Weight	60.055
Flash Point	32.2±22.6 °C
Exact Mass	60.032364
PSA	55.12000
LogP	-2.05
Vapour Pressure	10.0±0.2 mmHg at 25°C
Index of Refraction	1.424
Storage condition	2-8°C
Water Solubility	Soluble

formohydrazide MSDS(Chinese)

CHEMICAL IDENTIFICATION

RTECS NUMBER :: LQ8615000

CHEMICAL NAME :: Formic acid, hydrazide

CAS REGISTRY NUMBER :: 624-84-0

BEILSTEIN REFERENCE NO. :: 0635759

LAST UPDATED :: 199701

DATA ITEMS CITED :: 5

MOLECULAR FORMULA :: C-H4-N2-O

MOLECULAR WEIGHT :: 60.07

WISWESSER LINE NOTATION :: ZMVH

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Subcutaneous

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 120 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: ARZNAD Arzneimittel-Forschung. Drug Research. (Editio Cantor Verlag, Postfach 1255, W-7960 Aulendorf, Fed. Rep. Ger.) V.1- 1951- Volume(issue)/page/year: 18,645,1968

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 65 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: JMPCAS Journal of Medicinal and Pharmaceutical Chemistry. (Washington, DC) V.1-5, 1959-62. For publisher information, see JMCMAR. Volume(issue)/page/year: 4,259,1961 ** TUMORIGENIC DATA **

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 73 gm/kg/43W-C

TOXIC EFFECTS :: Tumorigenic - neoplastic by RTECS criteria Lungs, Thorax, or Respiration - tumors

REFERENCE :: BJCAAI British Journal of Cancer. (Macmillan Press Ltd., Houndmills, Basingstoke, Hants. RG21 2XS, UK) V.1- 1947- Volume(issue)/page/year: 37,960,1978 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X4064 No. of Facilities: 17 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 919 (estimated) No. of Female Employees: 306 (estimated)

Symbol	GHS07
Signal Word	Warning
Hazard Statements	H315-H319-H335
Precautionary Statements	P305 + P351 + P338
Personal Protective Equipment	dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes	Xn:Harmful;
Risk Phrases	R20/21/22;R36/37/38
Safety Phrases	S26-S36-S36/37/39
RIDADR	NONH for all modes of transport
WGK Germany	3
RTECS	LQ8615000
HS Code	2928000090

Ethyl formate

CAS#:109-94-4

~91%

formohydrazide

CAS#:624-84-0

Literature: Danagulyan; Tadevosyan; Tamazyan; Panosyan Chemistry of Heterocyclic Compounds, 2006 , vol. 42, # 2 p. 233 - 245

methyl formate

CAS#:107-31-3

formohydrazide

CAS#:624-84-0

Literature: Hoppe-Seyler's Zeitschrift fur Physiologische Chemie, , vol. 358, # 9 p. 1081 - 1091

Formic Acid

CAS#:64-18-6

~62%

formohydrazide

CAS#:624-84-0

Literature: Werner, Wolfgang; Depreux, Patrick Journal of Chemical Research, Miniprint, 1980 , # 11 p. 4513 - 4521

Methanol

CAS#:67-56-1

Ethyl formate

CAS#:109-94-4

formohydrazide

CAS#:624-84-0

Literature: Chemische Berichte, , vol. 84, p. 469 Chemische Berichte, , vol. 86, p. 547,550

Nitrogen

CAS#:7727-37-9

Ethyl formate

CAS#:109-94-4

formohydrazide

CAS#:624-84-0

Literature: EP1186599 A1, ; Page 23 ;

Precursor 5
CAS#:109-94-4 Ethyl formate CAS#:107-31-3 methyl formate CAS#:64-18-6 Formic Acid CAS#:67-56-1 Methanol
CAS#:7727-37-9 Nitrogen
DownStream 9
CAS#:10570-40-8 4-Methyl-4H-1,2... CAS#:3880-50-0 1-Methylethylid... CAS#:5373-72-8 3H-1,2,4-Triazo... CAS#:3451-51-2 2-methyl-1,3,4-...
CAS#:18039-42-4 5-Phenyl-1H-tet... CAS#:188113-56-6 4-hexadecyl-1,2... CAS#:102-08-9 Thiocarbanilide CAS#:27104-95-6 4-propyl-1,2,4-...
CAS#:27105-98-2 4-Ethyl-4H-1,2,...

HS Code	2928000090
Summary	2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

N-ethyl-N-formylhydrazine tumorigenesis in mice.

Carcinogenesis 1(1) , 61-5, (1980)

N-ethyl-N-formylhydrazine (EFH) was administered as a 0.02% solution in drinking water continuously for life to randomly bred Swiss mice, from 6 weeks of age. The treatment induced tumors of the lungs...

Traceless liquid-phase synthesis of 3-alkylamino-4, 5-disubstituted-1, 2, 4-triazoles on polyethylene glycol (PEG). Zong Y-X, et al.

Tetrahedron Lett. 46(31) , 5139-41, (2005)

Synthesis of NB-506, a new anticancer agent. Ohkubo M, et al.

Tetrahedron 53(2) , 585-92, (1997)

MFCD00007589

Formic hydrazide

formohydrazide

formic acid hydrazide

Hydrazine, formyl-

EINECS 210-867-9

Shanghai Jizhi Biochemical Technology Co., Ltd
China
Product Name: formohydrazide
Price: ￥308.0/25g ￥108.0/5g
Purity: 98.0%
Stocking Period: 2 Day
Contact: Liu jia

Dayang Chem (Hangzhou) Co., Ltd.
China
Product Name: Formylhydrazine
Price: $Inquiry/100g $Inquiry/1kg $Inquiry/100kg $Inquiry/1000kg
Purity: 98.0%
Stocking Period: Inquiry
Contact: Ms Wang

Zhejiang Hangyu API Co., Ltd
China
Product Name: Formylhydrazine
Price: ￥Inquiry/1kg
Purity: 99.5%
Stocking Period: Inquiry
Contact: Vinnie

Henan Tianfu Chemical Co., Ltd.
China
Product Name: Formylhydrazine
Price: $Inquiry/1kg $Inquiry/25kg $Inquiry/1000kg $Inquiry/10ton
Purity: 99.0%
Stocking Period: Inquiry
Contact: Anson

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