Trimethylsilyl acetate structure
|
Common Name | Trimethylsilyl acetate | ||
|---|---|---|---|---|
| CAS Number | 2345-38-2 | Molecular Weight | 132.233 | |
| Density | 0.9±0.1 g/cm3 | Boiling Point | 107.5±0.0 °C at 760 mmHg | |
| Molecular Formula | C5H12O2Si | Melting Point | 39-42 °C(lit.) | |
| MSDS | Chinese USA | Flash Point | 4.4±0.0 °C | |
| Symbol |
GHS07 |
Signal Word | Warning | |
| Name | (trimethylsilyl)acetic acid |
|---|---|
| Synonym | More Synonyms |
| Density | 0.9±0.1 g/cm3 |
|---|---|
| Boiling Point | 107.5±0.0 °C at 760 mmHg |
| Melting Point | 39-42 °C(lit.) |
| Molecular Formula | C5H12O2Si |
| Molecular Weight | 132.233 |
| Flash Point | 4.4±0.0 °C |
| Exact Mass | 132.060654 |
| PSA | 37.30000 |
| LogP | 1.24 |
| Vapour Pressure | 27.0±0.2 mmHg at 25°C |
| Index of Refraction | 1.391 |
| InChIKey | JDMMZVAKMAONFU-UHFFFAOYSA-N |
| SMILES | C[Si](C)(C)CC(=O)O |
| Storage condition | 2-8°C |
| Symbol |
GHS07 |
|---|---|
| Signal Word | Warning |
| Hazard Statements | H315-H319-H335 |
| Precautionary Statements | P261-P305 + P351 + P338 |
| Personal Protective Equipment | dust mask type N95 (US);Eyeshields;Gloves |
| Hazard Codes | Xi:Irritant; |
| Risk Phrases | R36/37/38 |
| Safety Phrases | S26-S36 |
| RIDADR | UN3261 |
| WGK Germany | 2 |
| RTECS | AK0843500 |
| Packaging Group | III |
| Hazard Class | 8 |
| HS Code | 2931900090 |
|
~88%
Trimethylsilyl ... CAS#:2345-38-2 |
| Literature: Sommer et al. Journal of the American Chemical Society, 1949 , vol. 71, p. 1509 |
|
~59%
Trimethylsilyl ... CAS#:2345-38-2 |
| Literature: Emde, Herbert; Simchen, Gerhard Liebigs Annalen der Chemie, 1983 , # 5 p. 816 - 834 |
|
~70%
Trimethylsilyl ... CAS#:2345-38-2 |
| Literature: Shtelman, Alex V.; Becker, James Y. Tetrahedron Letters, 2008 , vol. 49, # 19 p. 3101 - 3103 |
|
~%
Trimethylsilyl ... CAS#:2345-38-2 |
| Literature: Tetrahedron Letters, , vol. 32, # 7 p. 847 - 850 |
|
~%
Trimethylsilyl ... CAS#:2345-38-2 |
| Literature: Bulletin of the Chemical Society of Japan, , vol. 59, # 9 p. 2851 - 2860 |
|
~%
Trimethylsilyl ... CAS#:2345-38-2 |
| Literature: Journal of the American Chemical Society, , vol. 71, p. 1509 Journal of the American Chemical Society, , vol. 69, p. 1551 |
|
~%
Trimethylsilyl ... CAS#:2345-38-2 |
| Literature: Canadian Journal of Chemistry, , vol. 48, p. 561 - 569 |
| HS Code | 2931900090 |
|---|---|
| Summary | 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0% |
|
P.A. Grieco et al.
J. Chem. Soc. Chem. Commun. , 537, (1975)
|
|
|
D.H. Lucast, J. Wemple
Tetrahedron Lett. , 1103, (1977)
|
|
|
G.A. Olah et al.
Synthesis , 568, (1989)
|
| MFCD00042651 |
| Trimethylsilylacetic acid |
| trimethylsilanyl-acetic acid |
| Silanol, 1,1,1-trimethyl-, acetate |
| 2-(Trimethylsilyl)ethansaeure |
| (trimethylsilyl)-aceticaci |
| Acetic acid, trimethylsilyl ester |
| Silanol, trimethyl-, acetate |
| 2-(Trimethylsilyl)acetic acid |
| EINECS 219-067-4 |
| Trimethylsilyl acetate |
| me3SiCH2cox |