Methyl (trimethylsilyl)acetate
Modify Date: 2025-08-25 13:03:34
Methyl (trimethylsilyl)acetate structure
|
Common Name | Methyl (trimethylsilyl)acetate | ||
|---|---|---|---|---|
| CAS Number | 2916-76-9 | Molecular Weight | 146.260 | |
| Density | 0.9±0.1 g/cm3 | Boiling Point | 140.8±0.0 °C at 760 mmHg | |
| Molecular Formula | C6H14O2Si | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | 32.8±0.0 °C | |
| Symbol |
GHS02, GHS07 |
Signal Word | Warning | |
| Name | methyl 2-trimethylsilylacetate |
|---|---|
| Synonym | More Synonyms |
| Density | 0.9±0.1 g/cm3 |
|---|---|
| Boiling Point | 140.8±0.0 °C at 760 mmHg |
| Molecular Formula | C6H14O2Si |
| Molecular Weight | 146.260 |
| Flash Point | 32.8±0.0 °C |
| Exact Mass | 146.076309 |
| PSA | 26.30000 |
| LogP | 1.73 |
| Vapour Pressure | 6.0±0.2 mmHg at 25°C |
| Index of Refraction | 1.399 |
| InChIKey | JIHUZDFFYVRXKP-UHFFFAOYSA-N |
| SMILES | COC(=O)C[Si](C)(C)C |
| Storage condition | Flammables area |
| Symbol |
GHS02, GHS07 |
|---|---|
| Signal Word | Warning |
| Hazard Statements | H226-H315-H319-H335 |
| Precautionary Statements | P261-P305 + P351 + P338 |
| Personal Protective Equipment | Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
| Hazard Codes | F: Flammable;Xi: Irritant; |
| Risk Phrases | R11 |
| Safety Phrases | 16-26-36 |
| RIDADR | UN 3272 3/PG 3 |
| WGK Germany | 3 |
| Packaging Group | II |
| Hazard Class | 3.1 |
| HS Code | 2931900090 |
| HS Code | 2931900090 |
|---|---|
| Summary | 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0% |
|
Conjugate addition of lithiotrimethylsilylacetate. A simple synthesis of methyl jasmonate via vicinal double alkylation. Nishiyama H, et al.
Tetrahedron Lett. 25(23) , 2487-88, (1984)
|
|
|
Z-Isomers of Steroid 17ß-Side Chain Methyl Acrylates. Pouzar V, et al.
Collect. Czech. Chem. Commun. 57(9) , 1928-36, (1992)
|
| methyl 2-(trimethylsilyl)acetate |
| TMSCH2CO2Me |
| JIHUZDFFYVRXKP-UHFFFAOYSA |
| Acetic acid, 2-(trimethylsilyl)-, methyl ester |
| EINECS 220-845-0 |
| MFCD00008450 |
| (Me)3SiCH2CO2Me |
| Methyl (trimethylsilyl)acetate |
| methy C-(trimethylsilyl)acetate |
| Methyl(trimethylsilyl)acetate |
| Me3SiCH2CO2CH3 |
| (carbomethoxymethyl)trimethylsilane |