(Allyloxy)benzene

Modify Date: 2024-01-04 13:44:05

(Allyloxy)benzene Structure
(Allyloxy)benzene structure
Common Name (Allyloxy)benzene
CAS Number 1746-13-0 Molecular Weight 134.175
Density 0.9±0.1 g/cm3 Boiling Point 192.4±9.0 °C at 760 mmHg
Molecular Formula C9H10O Melting Point N/A
MSDS Chinese USA Flash Point 62.8±0.0 °C

 Names

Name Allyl Phenyl Ether
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.9±0.1 g/cm3
Boiling Point 192.4±9.0 °C at 760 mmHg
Molecular Formula C9H10O
Molecular Weight 134.175
Flash Point 62.8±0.0 °C
Exact Mass 134.073166
PSA 9.23000
LogP 2.94
Vapour Pressure 0.7±0.4 mmHg at 25°C
Index of Refraction 1.504
Water Solubility insoluble

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
DA8575000
CHEMICAL NAME :
Benzene, (2-propenyloxy)-
CAS REGISTRY NUMBER :
1746-13-0
BEILSTEIN REFERENCE NO. :
1905622
LAST UPDATED :
199701
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C9-H10-O
MOLECULAR WEIGHT :
134.19
WISWESSER LINE NOTATION :
1U2OR

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
100 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD277-689
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
63 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#01855 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - E0737 No. of Facilities: 20 (estimated) No. of Industries: 1 No. of Occupations: 3 No. of Employees: 1929 (estimated) No. of Female Employees: 81 (estimated)

 Safety Information

Personal Protective Equipment Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xn
Safety Phrases S24/25
RIDADR NA 1993 / PGIII
WGK Germany 3
RTECS DA8575000
HS Code 2909309090

 Synthetic Route

 Customs

HS Code 2909309090
Summary 2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

 Articles3

More Articles
SmI2/water/amine mediates cleavage of allyl ether protected alcohols: application in carbohydrate synthesis and mechanistic considerations.

Org. Lett. 5(22) , 4085-8, (2003)

[reaction: see text]. SmI2/H2O/amine provides selective cleavage of unsubstituted allyl ethers in good to excellent yields. This method is therefore useful in deprotection of alcohols and carbohydrate...

Pd-catalyzed synthesis of allylic silanes from allylic ethers.

Org. Lett. 12(1) , 28-31, (2010)

Allylic phenyl ethers serve as electrophiles toward Pd(0) en route to a variety of allylic silanes. The reactions can be run at room temperature in water as the only medium using micellar catalysis.

Stereoselective epoxidation of phenyl allyl ether by alkene-utilizing bacteria.

Appl. Microbiol. Biotechnol. 37(1) , 28-31, (1992)

Eighteen newly isolated ethene- and propene-utilizing bacteria were screened for the ability to produce phenyl glycidyl ether, a common precursor for the synthesis of beta blockers, from phenyl allyl ...

 Synonyms

Allyl phenyl ether
(Allyloxy)benzene
MFCD00008644
prop-2-enoxybenzene
EINECS 217-125-3
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