2-Methylthiirane

Modify Date: 2024-01-03 18:12:45

2-Methylthiirane Structure
2-Methylthiirane structure
Common Name 2-Methylthiirane
CAS Number 1072-43-1 Molecular Weight 74.145
Density 1.0±0.1 g/cm3 Boiling Point 75.9±8.0 °C at 760 mmHg
Molecular Formula C3H6S Melting Point N/A
MSDS Chinese USA Flash Point 10.0±0.0 °C
Symbol GHS02 GHS06
GHS02, GHS06
Signal Word Danger

 Names

Name propylene sulfide
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.0±0.1 g/cm3
Boiling Point 75.9±8.0 °C at 760 mmHg
Molecular Formula C3H6S
Molecular Weight 74.145
Flash Point 10.0±0.0 °C
Exact Mass 74.019020
PSA 25.30000
LogP 0.70
Vapour Pressure 113.2±0.1 mmHg at 25°C
Index of Refraction 1.520
Storage condition 2-8°C

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TZ2625000
CHEMICAL NAME :
Propane, 1,2-epithio-
CAS REGISTRY NUMBER :
1072-43-1
BEILSTEIN REFERENCE NO. :
0383559
LAST UPDATED :
199701
DATA ITEMS CITED :
6
MOLECULAR FORMULA :
C3-H6-S
MOLECULAR WEIGHT :
74.15
WISWESSER LINE NOTATION :
T3STJ B1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
254 mg/kg
TOXIC EFFECTS :
Behavioral - general anesthetic Lungs, Thorax, or Respiration - structural or functional change in trachea or bronchi Lungs, Thorax, or Respiration - respiratory depression
REFERENCE :
AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 25,560,1964
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
660 ppm/6H
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - fibrosis, focal (pneumoconiosis) Lungs, Thorax, or Respiration - acute pulmonary edema Blood - hemorrhage
REFERENCE :
BECTA6 Bulletin of Environmental Contamination and Toxicology. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 07094) V.1- 1966- Volume(issue)/page/year: 6,509,1971
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
44 mg/kg
TOXIC EFFECTS :
Peripheral Nerve and Sensation - flaccid paralysis without anesthesia (usually neuromuscular blockage) Behavioral - ataxia Lungs, Thorax, or Respiration - cyanosis
REFERENCE :
AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 25,560,1964
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
400 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
RAREAE Radiation Research. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1954- Volume(issue)/page/year: 7,13,1957 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X7180 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 1822 (estimated) No. of Female Employees: 272 (estimated)

 Safety Information

Symbol GHS02 GHS06
GHS02, GHS06
Signal Word Danger
Hazard Statements H225-H301-H315-H319-H332
Precautionary Statements P210-P301 + P310-P305 + P351 + P338
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes F: Flammable;Xn: Harmful;
Risk Phrases 11-20/22-36/38
Safety Phrases S16-S26-S36
RIDADR UN 1992 3/PG 2
WGK Germany 3
RTECS TZ2625000
Packaging Group II
Hazard Class 3.1

 Synthetic Route

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 Synonyms

Thiirane, 2-methyl-
Methylethylene Sulfide
MFCD00005160
2-Methylthiirane
EINECS 214-007-3
Propylene sulfide